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  • 1
    Publication Date: 2019-07-13
    Description: The Mars rover Curiosity has encountered silica-enriched bedrock (as strata and as veins and associated halos of alteration) in the largely basaltic Murray Fm. of Mt. Sharp in Gale Crater. Alpha Particle X-ray Spectrometer (APXS) investigations of the Murray Fm. revealed decreasing Mg, Ca, Mn, Fe, and Al, and higher S, as silica increased (Fig. 1). A positive correlation between SiO2 and TiO2 (up to 74.4 and 1.7 wt %, respectively) suggests that these two insoluble elements were retained while acidic fluids leached more soluble elements. Other evidence also supports a silica-retaining, acidic alteration model for the Murray Fm., including low trace element abundances consistent with leaching, and the presence of opaline silica and jarosite determined by CheMin. Phosphate stability is a key component of this model because PO4 3- is typically soluble in acidic water and is likely a mobile ion in diagenetic fluids (pH less than 5). However, the Murray rocks are not leached of P; they have variable P2O5 (Fig. 1) ranging from average Mars (0.9 wt%) up to the highest values in Gale Crater (2.5 wt%). Here we evaluate APXS measurements of Murray Fm. bedrock and veins with respect to phosphate stability in acidic fluids as a test of the acidic alteration model for the Lower Mt. Sharp rocks.
    Keywords: Lunar and Planetary Science and Exploration
    Type: JSC-CN-35224 , Lunar and Planetary Science Conference; Mar 21, 2016 - Mar 25, 2016; The Woodlands, TX; United States
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  • 2
    Publication Date: 2019-07-19
    Description: The Mars Science Laboratory rover Curiosity has traversed up section through approximately 100 m of sedimentary rocks deposited in fluvial, deltaic, lacustrine, and eolian environments (Bradbury group and overlying Mount Sharp group). The Stimson formation unconformably overlies a lacustrine mudstone at the base of the Mount Sharp group and has been interpreted to be a cross-bedded sandstone of lithified eolian dunes. Unaltered Stimson sandstone has a basaltic composition similar to the average Mars crustal composition, but is more variable and ranges to lower K and higher Al. Fluids passing through alteration "halos" adjacent to fractures have altered the chemistry and mineralogy of the sandstone. Elemental mass gains and losses in the alteration halos were quantified using immobile element concentrations, i.e., Ti (taus). Alteration halos have elemental gains in Si, Ca, S, and P and large losses in Al, Fe, Mn, Mg, Na, K, Ni, and Zn. Mineralogy of the altered Stimson is dominated by Ca-sulfates, Si-rich X-ray amorphous materials along with plagioclase feldspar, magnetite, and pyroxenes. The igneous phases were less abundant in the altered sandstone with a lower pyroxene/plagioclase feldspar. Large elemental losses suggest acidic fluids initially removed these elements (Al mobile under acid conditions). Enrichments in Si, Ca, and S suggest secondary fluids (possibly alkaline) passed through these fractures leaving behind X-ray amorphous Si and Ca-sulfates. The mechanism for the large elemental gains in P is unclear. The geochemistry and mineralogy of the altered sandstone suggests a complicated diagenetic history with multiple episodes of aqueous alteration under a variety of environmental conditions (e.g., acidic, alkaline).
    Keywords: Lunar and Planetary Science and Exploration
    Type: JSC-CN-37384 , AGU Fall Meeting 2016; Dec 12, 2016 - Dec 16, 2016; San Francisco, CA; United States
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  • 3
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    Academy of Science of South Africa
    In:  South African Journal of Science, 97 (5-6). pp. 199-208.
    Publication Date: 2020-05-26
    Description: A multidisciplinary survey on board R.V. Poseidon off Angola and northern Namibia in April 1999 allowed a large-scale view of the South-East Atlantic boundary current system. The data set comprises meteorological, hydrographical, biological and chemical data. Sequences of satellite images of sea-surface temperature and wind stress provided additional synoptic information. Several mesoscale cyclonic gyres were observed embedded in a larger area of low dynamic height, known as the Angola Gyre. The most developed mesoscale feature was the subthermoclinal Angola Dome detected at 9 degreesS, 8.5 degreesE. At the beginning of April, the Angola-Benguela Frontal Zone (ABFZ) was found at an unusually southerly position near 19 degreesS. During the time of the cruise, the zone moved rapidly northward. The dynamics of this event are discussed in detail. The high-frequency temporal variations of the front were closely related to local wind forcing. Below the thermocline the conditions were more persistent. The ABFZ was represented as a front between different types of Central Water. The existence of a poleward undercurrent below the ABFZ, reported in recent publications, was not verified from direct current measurements. However, water mass distribution suggests overall poleward transport below the thermocline.
    Type: Article , PeerReviewed
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