ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The Pe(1), F″=2.5 branch feature of the (0,0) D 3Π0e–X 3Δ1 band system of 51VN was recorded as a function of an applied static electric field. The resultant Stark splitting and shifts were analyzed giving values of 3.07(7) D and 6.1(4) D for the X 3Δ1 and D 3Π0e states, respectively, for the magnitude of the permanent electric dipole moment, |μ|. Similarly, the Ree(0.5) branch feature of the (0,0) A 4Π3/2–X 4Σ− band system of 52CrN was recorded as a function of an applied static electric field and analyzed to produce |μ| values of 2.31(4) D and 5.42(2) D for the X 4Σ− and A 4Π3/2 states, respectively. In order to facilitate the dipole moment determinations for 52CrN it was necessary to record and analyze the field free spectrum of the (0,0) A 4Π3/2–X 4Σ− subband system. A comparison of the dipole moments for the first row monoxides and mononitrides is made and trends are discussed with reference to a molecular orbital correlation scheme. © 1999 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.478055
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