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  • Chemistry  (5)
  • GEOPHYSICS
  • METEOROLOGY AND CLIMATOLOGY
  • Meteorology and Climatology
  • 1995-1999  (6)
  • 1950-1954
  • 1998  (6)
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  • 1995-1999  (6)
  • 1950-1954
Year
  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 36 (1998), S. 1573-1582 
    ISSN: 0887-624X
    Keywords: amic acid ; secondary amine ; maleic anhydride ; melt reaction kinetics ; model compounds ; polymer-bound functional groups ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: This study examines the legitimacy of using the reaction kinetics of low molecular weight model compounds in solution to predict the chemical kinetics of polymer-bound species in a homogeneous melt. The reaction under study takes place between an aliphatic secondary amine, diisooctadecylamine (DiOA), and a 5-membered anhydride ring, saturated maleic anhydride (MA), forming an amic acid product. The MA species was present as a pendant graft on either a model compound, dodecane-g-(maleic anhydride) (dodecane-g-MA), or a polymer chain, linear low-density polyethylene-g-(maleic anhydride) (LLDPE-g-MA). Pseudo-second-order kinetics of the anhydride consumption are followed by infrared spectroscopy, either in situ in dodecane solution or by scanning frozen film samples taken from a linear low-density polyethylene melt. It was found that the LLDPE-g-MA/DiOA system reacted at a slightly slower rate than the dodecane-g-MA/DiOA system in the low-viscosity solution at 140°C. In the melt, the dodecane-g-MA/DiOA system experienced a small decrease in the overall reaction rate compared to the same reaction carried out in dodecane. However, the LLDPE-g-MA/DiOA system underwent a 65% decrease in the observed second-order rate constant on going from a solution to the melt. To explain these phenomena, the effects of diffusion, miscibility, and chain entanglements in the melt are examined here. © 1998 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 36: 1573-1582, 1998
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 17 (1998), S. 297-301 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The Baker-Strehlow methodology was developed to provide an objective approach to prediction of blast pressures from vapor cloud explosions. The complete methodology was first published in 1994 [1]. Since then, it has evolved through ongoing research and use in VCE hazard analyses, facility siting studies and accident investigations. This article gives a brief overview of a paper on recent developments in the Baker-Strehlow methodology presented at the 31st Loss Prevention Symposium in Houston on March 9-13, 1997. Because the entire paper is too lengthy to be presented here, the following discussions may be lacking in some details. A copy of the complete paper can be obtained from the American Institute of Chemical Engineers (AIChE).Since the Baker-Strehlow method was first published, it has been used extensively in VCE hazard assessments in refineries and chemical plants. As expected, many practical lessons have been learned during the course of the hazard assessments, and the Baker-Strehlow method has evolved as a result. The changes have been evolutionary, not revolutionary. In keeping with the goals of the original study in which the methodology was developed, all changes have been incorporated with the intent of achieving an objective methodology to provide consistent prediction of VCE blast effects.The revisions to the Baker-Strehlow method resulting from experience gained during plant walk-downs and hazard assessments include: Systematic identification of “potential explosion sites” or “PESs,”Selection of the level of confinement for mixed zones of 2D and 3D confinement,Deciding on flame expansion when confinement is elevated above the vapor cloud,Selecting the reactivity for a fuel that is a mixture of fuels with differing reactivities,Predicting blast loads when there are multiple PES's within a vapor cloud considering different ignition source locations.
    Additional Material: 4 Ill.
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  • 3
    ISSN: 0021-9304
    Keywords: bovine platelets ; platelet activation ; flow cytometry ; biocompatibility assays ; ventricular-assist devices ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Cardiovascular device development often relies upon large-animal models to assess blood biocompatibility prior to initiating clinical trials. Unfortunately, the amount of information gleaned from such trials is limited by simple assays that do not take full advantage of immuno-technological advances that increasingly are applied in clinical studies. Thus we have developed and tested new flow cytometric techniques for measuring circulating activated bovine platelets and platelet microaggregates. Monoclonal antibodies (MAbs) raised against both activated and quiescent bovine platelets were incubated with control and PMA- or ADP-stimulated whole blood. Selected MAbs detected activated bovine platelets and platelet microaggregates in vitro with flow cytometry. Five calves implanted with one of two designs of nonpulsatile ventricular-assist devices (VADs) were followed with these assays prior to and during VAD implantation. Circulating activated bovine platelets and microaggregates increased after implantation in all animals and, alternatively, remained elevated or returned toward preimplant levels. Platelet activation percentages as detected temporally by three MAbs were correlated with one another, and platelet activation was correlated with microaggregate formation. In summary, these new methods for the sensitive measurement of circulating activated bovine platelets and microaggregates may provide valuable information for the development and assessment of future cardiovascular device designs. © 1998 John Wiley & Sons, Inc. J Biomed Mater Res, 41, 312-321, 1998.
    Additional Material: 8 Ill.
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  • 4
    ISSN: 0021-9304
    Keywords: calcium phosphate(s) ; brushite ; hydroxyapatite ; calcite ; remodeling ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Four calcium phosphate cement formulations were implanted in the rabbit distal femoral metaphysis and middiaphysis. Chemical, crystallographic, and histological analyses were made at 2, 4, and 8 weeks after implantation. When implanted into the metaphysis, part of the brushite cement was converted into carbonated apatite by 2 weeks. Some of the brushite cement was removed by mononuclear macrophages prior to its conversion into apatite. Osteoclastlike cell mediated remodeling was predominant at 8 weeks after brushite had converted to apatite. The same histological results were seen for brushite plus calcite aggregate cement, except with calcite aggregates still present at 8 weeks. However, when implanted in the diaphysis, brushite and brushite plus calcite aggregate did not convert to another calcium phosphate phase by 4 weeks. Carbonated apatite cement implanted in the metaphysis did not transform to another calcium phosphate phase. There was no evidence of adverse foreign body reaction. Osteoclastlike cell mediated remodeling was predominant at 8 weeks. The apatite plus calcite aggregate cement implanted in the metaphysis that was not remodeled remained as poorly crystalline apatite. Calcite aggregates were still present at 8 weeks. There was no evidence of foreign body reaction. Osteoclastlike cell remodeling was predominant at 8 weeks. Response to brushite cements prior to conversion to apatite was macrophage dominated, and response to apatite cements was osteoclast dominated. Mineralogy, chemical composition, and osseous implantation site of these calcium phosphates significantly affected their in vivo host response. © 1998 John Wiley & Sons, Inc. J Biomed Mater Res (Appl Biomater) 43: 451-461, 1998
    Additional Material: 13 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Computational Chemistry 19 (1998), S. 1187-1204 
    ISSN: 0192-8651
    Keywords: vibrational spectra ; SQM force fields ; fluorocarbons ; density functional theory ; Chemistry ; Theoretical, Physical and Computational Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Computer Science
    Notes: Using the scaled quantum-mechanical (SQM) force field approach with direct scaling of individual primitive force constants, we derive optimal scaling factors by a least-squares fit to the experimentally observed fundamentals of some selected “simple” fluorocarbons. We use the derived scaling factors to predict the vibrational spectra of all possible fluoromethanes, fluoroethylenes, fluoroethanes, and monofluoropropenes, proposing a reassignment of some experimental fundamentals. Two separate sets of scaling factors are derived for both traditional Hartree-Fock (HF) calculations and density functional theory (DFT) calculations using the hybrid three-parameter B3-PW91 density functional. With the split-valence 6-31G(d) basis set, our scaling procedure gives an average error of less than 9 cm-1 in the scaled frequencies with the B3-PW91 functional. The average percentage error is around 1%. The HF results are not as good - the average error is 12.6 cm-1 - showing that hybrid density functional SQM schemes are better for predicting vibrational spectra than basic Hartree-Fock.   © 1998 John Wiley & Sons, Inc.   J Comput Chem 19: 1187-1204, 1998
    Additional Material: 2 Ill.
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  • 6
    Publication Date: 2019-07-17
    Description: Land surface processes play a key role in water and energy budgets of the hydrological cycle. For example, the distribution of soil moisture will affect sensible and latent heat fluxes, which in turn may dramatically influence the location and intensity of precipitation. However, mean wind conditions also strongly influence the distribution of precipitation. The relative importance of soil moisture and wind on rainfall location and intensity remains uncertain. Here, we examine the influence of soil moisture distribution and wind distribution on precipitation in the Florida peninsula using the 3-D Goddard Cumulus Ensemble (GCE) cloud model Coupled with the Parameterization for Land-Atmosphere-Cloud Exchange (PLACE) land surface model. This study utilizes data collected on 27 July 1991 in central Florida during the Convection and Precipitation Electrification Experiment (CaPE). The idealized numerical experiments consider a block of land (the Florida peninsula) bordered on the east and on the west by ocean. The initial soil moisture distribution is derived from an offline PLACE simulation, and the initial environmental wind profile is determined from the CaPE sounding network. Using the factor separation technique, the precise contribution of soil moisture and wind to rainfall distribution and intensity is determined.
    Keywords: Meteorology and Climatology
    Type: Dec 06, 1998 - Dec 10, 1998; San Francisco, CA; United States
    Format: text
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