ALBERT

Notes: A negative-ion source extraction model has been formulated and implemented that explicitly considers the motion of positive ions and the volume generation of negative ions. It is found that (1) for high-beam currents, the beam current is limited by a transverse space-charge limit, meaning that an increase in negative-ion density at the extraction sheath will result in a lower-beam current (this result is universally observed at high-beam current); (2) there is a saddle point with a potential barrier preventing most volume-produced negative ions from being extracted [the combination of (1) and (2) indicates that most of the negative ions being created do not find their way into the beam]; (3) the introduction of cesium may cause an increase in the transverse space-charge limit; (4) cesium also results in an increase in the fraction of volume-produced negative ions that are extracted; (5) cesium may also result in reduction of extracted electrons by producing a less negative bias on the plasma electrode with respect to the plasma, thus allowing the transverse space-charge limit budget to be taken up virtually totally by the ions. [The combination of (3)–(5) represents the way an actual increase in the beam current can be achieved]; (6) a strong ion time scale sheath instability due to violation of the Bohm criteria produces an anomalous ion temperature, which increases with the beam current, as routinely seen in measurements; and (7) the introduction of cesium may result in a reduction in this instability. These insights may lead to improvements in volume negative-ion sources.

Notes: Invasion of coastal dunes by Lupinus arboreus (yellow bush lupine) results in soil enrichment and displacement of native plants. Restoration by means of heavy equipment was tested as an alternative to costly manual techniques in a heavily invaded area of relatively flat terrain. Two experiments were conducted in consecutive years at the Eureka Dunes Protected Area in Humboldt County, California. Each experiment consisted of three plots subjected to one of three primary treatments: removal of vegetation with a brush rake, removal of vegetation with a brush rake followed by removal of litter and duff with a plough blade or bucket, and removal of vegetation with tractor-pulled chokers. Plots were then subdivided into smaller secondary treatment plots subjected to one of two treatments or a control. Secondary treatments consisted of weedmat placed for a 1- or 2-year duration. The goal of the treatments was to remove and prevent reestablishment of nonnative vegetation, including but not limited to bush lupine; success was measured by percent cover of recolonizing vegetation 1.5 years after treatment ended. In the first experiment, primary treatment (vegetation removal) but not secondary (prevention of reestablishment) resulted in significant differences in cover by the end of the experiment. The brush rake and plough blade treatment was most successful at preventing reestablishment of nonnative vegetation. In the second experiment, secondary treatment (prevention of reestablishment) but not primary (removal of vegetation) resulted in significant differences at the end of the experiment. Re-invasion increased with the amount of time subplots were left uncovered. The difference in the results of the first and second experiments was attributed to variation in rainfall and, to a lesser extent, to localized variation in species composition. Results suggest that mechanical restoration by means of combination of the brush rake and plough blade primary treatment with the 2-year weedmat secondary treatment would be most successful in meeting the dual goals of removal of nonnative vegetation and prevention of its reestablishment.

Notes: The concept of the return period is widely used in the analysis of the risk of extreme events and in engineering design. For example, a levee can be designed to protect against the 100-year flood, the flood which on average occurs once in 100 years. Use of the return period typically assumes that the probability of occurrence of an extreme event in the current or any future year is the same. However, there is evidence that potential climate change may affect the probabilities of some extreme events such as floods and droughts. In turn, this would affect the level of protection provided by the current infrastructure. For an engineering project, the risk of an extreme event in a future year could greatly exceed the average annual risk over the design life of the project. An equivalent definition of the return period under stationary conditions is the expected waiting time before failure. This paper examines how this definition can be adapted to nonstationary conditions. Designers of flood control projects should be aware that alternative definitions of the return period imply different risk under nonstationary conditions. The statistics of extremes and extreme value distributions are useful to examine extreme event risk. This paper uses a Gumbel Type I distribution to model the probability of failure under nonstationary conditions. The probability of an extreme event under nonstationary conditions depends on the rate of change of the parameters of the underlying distribution.

Notes: Within the generalized gradient approximation (GGA) of density functional theory (DFT) we have calculated a three-dimensional (3D) potential energy surface (PES) including an angular degree of freedom for a H2 molecule interacting with a Pd(111) surface. There is an entrance channel barrier ((approximate)0.09 eV) to both dissociative chemisorption and direct subsurface absorption, but after this barrier is crossed direct subsurface absorption can proceed almost without a barrier. 3D quantum mechanical wave packet calculations incorporating the rotation of H2 in a plane perpendicular to the surface show a large part of the hydrogen going directly subsurface even at low incident kinetic energies. The wave packet calculations also show that in the low energy regime rotation inhibits direct subsurface absorption at low j0 and promotes it at high j0. © 1998 American Institute of Physics.

Notes: We have conducted a study of electron-stimulated reactions in butanethiol, octanethiol, dodecanethiol, and hexadecanethiol monolayers adsorbed onto Au/mica substrates, using in situ infrared spectroscopy to quantify the processes; the electron dose dependence of the depletion of various C–H stretching modes has permitted the determination of the first dissociation cross sections for electron stimulated reactions in self-assembled organic monolayers. Electron-induced dehydrogenation of alkanethiol/Au/mica films in the 0–15 eV regime is shown to proceed principally via dissociative electron attachment, thus confirming previous work that directly measured H2 desorption yields during irradiation. The dissociation probabilities exhibit a well-resolved maximum at 10 eV, with a full-width at half-maximum of ∼4 eV. Unlike previous studies, our spectroscopic investigation shows that the dehydrogenation is not uniformly distributed throughout the organic film, but is strongly localized near the methyl terminations of the film. The dissociation cross sections at this interface increase rapidly with increasing chain length. We have shown that these increases are not due to the interaction of the dissociative anionic state with the film via charge-induced dipole forces, nor are they due to interactions with the metal substrate via charge-image charge forces. Our results are consistent with a dipole-image dipole quenching model, whereby the excited state lifetimes are reduced from an estimated ∼26 fs (for a gas-phase electron-alkane collision) to ∼2–10 fs, depending on the chain length. These distance-dependent lifetimes cause the dissociation yields for short-chain systems to be significantly lower than long-chain systems, and it is predicted that the electron-induced dissociation cross sections for alkanethiol monolayers should show much stronger isotopic dependencies than found with the gas-phase alkane species. © 1998 American Institute of Physics.

Notes: To study the influence of temperature on the nutrient and fatty acid digestibility of salmonid fish, Arctic charr, Salvelinus alpinus L., were fed dry pelleted diets at 10 and 0.6 °C for 81 days. The diets had a carbohydrate/lipid content of 23.7/13% and 6.4/ 27% and a constant protein content of around 50%. At the end of feeding period, gut contents were collected from the mid- and hind-gut regions, and analysed for the apparent digestibility coefficient (ADC) of nutrients using chromic oxide as digestibility marker. Fish maintained at 0.6 °C had a lower ADC of protein, carbohydrate, lipid and dry matter compared to those maintained at 10 °C. This shows that increased gastrointestinal holding time following low temperature adaptation does not fully compensate for lowered digestive/absorptive metabolism. Feeding high carbohydrate diets had no significant influence on nutrient utilization at 10 °C, but appeared to reduce the ADC of most macronutrients at 0.6 °C. The ADC of the individual fatty acids increased with decreasing chain length and increased with unsaturation. Maintaining the fish at 0.6 °C significantly reduced the ADC of saturated fatty acids, while the monounsaturated fatty acids, and in particular, the polyunsaturated fatty acids were hardly influenced by environmental temperature. It is suggested that the reason may be a shift in digestive lipase specificity caused by changes in the substrate state or lowered solubilization of saturated fatty acids in bile micelles, which thus reduces the uptake into the enterocyte.

Notes: The aim of this paper is to explore the amusement park industry and its evolution during the 1990s. The primary causes of change in this industry are determined and their impact on the companies operating in this business is investigated. The assumption to be ascertained is how currently operating amusement park firms have been able to effectively respond to the threats and opportunities created by the environmental changes occurring in the 1990s. The analysis is framed into three main sections: first, it offers an overview of the amusement industry; second, it examines the environmental trends affecting it; and third, it attempts to delineate the future development of the amusement business.

Notes: [Auszug] Fever, hypotension and bleeding disorders are common symptoms of sepsis and septic shock. The activation of the contact-phase system is thought to contribute to the development of these severe disease states by triggering proinflammatory and procoagulatory cascades; however, the underlying ...

Notes: To compare the rates of digestion and absorption of individual fatty acids, Arctic charr, Salvelinus alpinus (L.), were fed isoenergetic diets containing 40 g kg−1 coconut oil, and various combinations of 10 g kg−1 of polyunsaturated fatty acids (PUFA) (18:2n-6 or 18:3n-3) and monounsaturated fatty acids (MONO) (20:1n-9 or 22:1n-9) in the form of free fatty acids (FFA) or triacylglycerol (TAG). The average lipid digestibility for all diets measured by use of the chromic oxide method in the pyloric caeca area, midgut and hindgut were 72%, 83% and 88%, respectively, showing that lipid digestion and absorption occur mainly in the pyloric caeca area, but also extend throughout the intestinal tract. Analyses of digesta present in the intestinal segments suggest the predominance of non-specific lipolytic activity producing primarily FFA and glycerol from dietary TAG. Comparisons of the fatty acid composition of the lipid classes in the digesta showed that the utilization of dietary TAG was dependent both on the rate of release of the individual fatty acids from TAG, and their subsequent rate of absorption. When supplied as either FFA or TAG, the levels of PUFA (18:2n-6 or 18:3n-3) in the digesta were very low, indicating almost complete utilization. Both MONO used (20:1n-9 or 22:1n-9) were absorbed less efficiently than PUFA, but the rate of release from TAG seemed to be rate limiting only for 22:1n-9, which accumulated in the digesta. The rates of absorption of 20:1n-9 and 22:1n-9 when fed as FFA were the same. Comparisons of the levels of fatty acids in the dietary coconut oil TAG with those of the digesta lipids showed that 12:0 was a good substrate for intestinal lipase and was quickly absorbed. The lipolysis of 14:0 and 16:0 was intermediate while the longer-chain 18:0 appeared very resistant to digestion and was a major component of TAG, diacylglycerols and monoacylglycerols present in particularly the hindgut digesta. The absorption of 18:0 also appeared to be very low. The results suggest that PUFA are released very rapidly from dietary TAG by intestinal lipases in Arctic charr, and are specifically absorbed compared with long-chain saturated and monounsaturated fatty acids. The rate of lipolysis may be the rate-limiting step in the digestion of very long chain monounsaturated fatty acids such as 22:1n-9, while both the rate of lipolysis and absorption may be rate limiting for long-chain saturated fatty acids such as 18:0.