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  • Aminoalkylation  (1)
  • Composite Materials  (1)
  • 2000-2004
  • 1995-1999  (2)
  • 2001
  • 1998  (2)
  • 1
    ISSN: 1434-193X
    Keywords: Mannich bases ; Aminoalkylation ; Lewis acids ; Aldehydes ; Diastereoselectivity ; Enantioselectivity ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: LiClO4-mediated one-pot reactions of aldehydes with (trimethylsilyl)dialkylamines 2, 5 or 19 and C nucleophiles such as enamines 3, 10 and 12, imines 7 and 11 or (trimethylsilyl)enol ethers 8 and 9 afforded the corresponding aminoalkylation products in high yields. Whereas by using aromatic aldehydes, such as benzaldehyde, pyridine-3-carbaldehyde or thiophene-2-carbaldehyde, high diasteroselectivity was achieved, the aminoalkylation of aliphatic aldehydes such as isobutyraldehyde and pivalaldehyde lacked diastereoselectivity. Enantioselective Mannich reactions using chiral enamines 22 and 23 are reported.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2019-07-13
    Description: Films reinforced with woven fabrics are being considered for the development of a material suitable for long duration scientific balloons under a program managed by the National Aeronautics and Space Administration (NASA). Recently developed woven fabrics provide a relatively high strength to weight ratio compared to standard homogenous films. Woven fabrics also have better crack propagation resistance and rip stop capabilities when compared to homogenous lightweight, high strength polymeric films such as polyester and nylon. If joining is required, such as in the case of scientific balloons, woven fabrics have the advantage over polymeric thin films to utilize traditional textile methods as well as other techniques including hot sealing, adhesion, and ultrasonic means. Woven fabrics, however, lack the barrier properties required for helium filled scientific balloons, therefore lamination with homogenous films is required to provide the gas barrier capabilities required in these applications.
    Keywords: Composite Materials
    Type: Composite Materials; Jul 05, 1998 - Jul 11, 1998; Las Vegas, NV; United States
    Format: application/pdf
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