ISSN:
0001-1541
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Process Engineering, Biotechnology, Nutrition Technology
Notes:
Bubble instabilities observed in film blowing using four different polyolefins are discussed: high-density polyethylene (HDPE), low-density polyethylene (LDPE), linear low-density polyethylene (LLDPE), and polypropylene (PP). Special attention is given to the effect of the frost line height on the bubble stability, an effect mostly ignored in the literature. A video-camera system was used to record the bubble shape and oscillations. In general, three forms of instabilities and combinations were observed: (1) axisymmetric periodic variations in the bubble diameter; (2) helical motions of the bubble; and (3) variations in the position of the solidification line. The four resins show different stability behaviors. The LDPE has the most stable operating space and the PP is the most unstable one. No correlation was observed between bubble stability and oscillatory shear rheological properties of the resins. Instability is enhanced by increasing take-up ratio, increasing blow-up ratio, and decreasing frost line height. Furthermore, for the LDPE, some operating points were not attainable and multiple steady states were observed. Our results are in a poor agreement with the predictions Cain and Denn's 1988 analysis.
Additional Material:
14 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/aic.690420519
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