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  • Engineering General  (36)
  • Chemical Engineering  (35)
  • Wiley-Blackwell  (71)
  • 1995-1999  (71)
  • 1996  (71)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 3055-3062 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The inverse probability theorem of Bayes is used, along with sampling theory, to obtain objective criteria for choosing among rival models. Formulas are given for the relative posterior probabilities of candidate models and for their goodness of fit, when the models are fitted to a common data set with Normally distributed errors. Cases of full, partial and minimal variance information are treated. The formulas are demonstrated with three examples, including a kinetic study of a catalytic reaction.
    Additional Material: 5 Tab.
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    International Journal for Numerical and Analytical Methods in Geomechanics 20 (1996), S. 119-141 
    ISSN: 0363-9061
    Keywords: inverse analysis ; parameter identification ; underground excavation ; optimization technique ; finite element method ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: A probabilistic framework to perform inverse analysis of geotechnical problems is presented. The formulation allows the incorporation of existing prior information on the parameters in a consistent way. The method is based on the maximum likelihood approach that allows a straightforward introduction of the error structure of field measurements and prior information. The difficulty of ascribing definite values to the uncertainties associated with the various types of observations is overcome by including the corresponding variances in the set of parameters to be identified. The inverse analysis results in a minimization problem that is solved by coupling the optimization technique to the finite element method. Two examples are presented to illustrate the performance of the method. The first one corresponds to a synthetic case simulating the excavation of a tunnel. Young's modulus, K0 value and measurements variances are identified. The second case concerns the excavation of a large underground cavern in which again Young's modulus and K0 are identified. It is shown that introduction of prior information permits the estimation of parameters more consistent with all available informations that include not only monitored displacements but also results from in situ tests carried out during the site investigation stage.
    Additional Material: 13 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 22 (1996), S. 1075-1087 
    ISSN: 0271-2091
    Keywords: capillary flow ; drag coefficient ; shear stress distribution ; ellipsoids ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A numerical scheme is developed to obtain the flow field around one, two and five ellipsoidal objects inside a cylindrical tube. The scheme uses the Galerkin finite element technique and the primitive variable(u-v-p) formulation. The two-dimensional incompressible Navier-Stokes equations are solved numerically by using the direct mixed interpolation method. A Picard iteration scheme is used for the solution of the resulting system of non-linear algebraic equations. The computer code is verified by checking with known analytical solutions for the flow past a sphere. Results for the shear stress distributions along the ellipsoids, forces and drag coefficients are obtained for different geometric ratios and Reynolds numbers. Some of the intermediate computational results on the velocity fields developed are also reported.
    Additional Material: 13 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 2036-2046 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An improved set of all the thermodynamic and molecular properties required for the prediction of the existing 20 systems of Structure H (sH) hydrate phase equilibrium data is presented. The statistical thermodynamics model was based on the van der Waals and Platteeuw theory, and the spherical core Kihara potential was used for guest-water interactions. Optimized Kihara parameters and reference thermodynamic properties were derived from experimental data of over 20 sH hydrate forming systems. The model could fit all the existing sH hydrate data within an accuracy of ± 6%. Inhibitor predictions were also shown to fit recent data with no adjustable parameters. The feasibility of using hydrate cage occupancies to derive refined Kihara parameters of the guest molecules was investigated. Possible existence of sH hydrates at cryogenic temperatures was also established based on the model.
    Additional Material: 20 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 2701-2712 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A general computational approach is presented for numerical modeling of viscous flow in baffled, impeller-stirred-tank reactors. A multiblock, body-fitted grid structure facilitates modeling of various impeller and baffle designs, and a new procedure offers averaged velocity data from a complex 3-D CFD dataset. Impellers are modeled precisely, eliminating the need for inputting experimental velocity data for boundary conditions. The method can be used quickly to obtain extremely detailed flow computations at a fraction of the cost of computing unsteady moving grid solutions. A steady-state computational approach that neglects the relative motion between impeller and baffles yields numerical results comparably accurate to full unsteady computations for laminar flow at a fraction of the time and expense. The approximate steady-state method is used to predict power requirements of a Rushton turbine in laminar flow.An unsteady, moving grid technique provides time-accurate solutions for the flow inside an impeller-stirred reactor with side-wall baffles. These computed results are compared with those using the approximate steady-state method and with experimental measurements. The unsteady, moving grid method uses two different initial conditions: one starting from rest and the other starting from an approximate steady-state solution obtained at the starting position of the impeller relative to the baffles. For unsteady simulations of laminar flow in stirred vessels, the final operating condition can be achieved much more efficiently if the solution obtained from the steady-state procedure is used as an approximate initial condition.
    Additional Material: 12 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 2743-2760 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: High-purity distillation columns are typically difficult to control because of their severely nonlinear behavior reflected by their sharp composition and temperature profiles. The dynamic behavior of such a column, as characterized by the movement of its sharp profile, was elucidated by a nonlinear wave theory established previously. With binary alcohol mixtures, this study provides an experimental observation of such wave-propagation dynamics of a 40-tray stripping column and a 50-tray fractionation column in response to step disturbances of feed composition, feed flow rate, and reboiler heat supply. Our experimental results have verified that the sharp profile in a high-purity column moves as a constant-pattern wave and that the nonlinear wave theory predicts its velocity satisfactorily with very simple mathematics. Our results also demonstrate the asymmetric dynamics of the transitions between two steady states.
    Additional Material: 10 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 861-875 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A primary constituent in high-temperature (120-140°C) milk fouling residues is calcium phosphate in the form of calcium phosphate dihydrate (brushite, CaHPO4 · 2H2O) and hydroxyapatite [Ca5(PO4)3OH]. The removal of these mineral-rich deposits from stainless steel occurs by dissolution and mechanical cleaning. This research uses a novel solid scintillation technique to noninvasively and continuously investigate the removal of P32-labeled mixtures of calcium phosphate from inner surface of stainless steel tubes. The proposed mass-transfer model suggests that the film is initialy removed by dissolution, when compared to the experimental results. An alternative first-order model presented includes the effects of the solvent flow rate and solvent pH on decontamination rates. This model agrees with the experimental cleaning data over the range of pH and flow rates studied.
    Additional Material: 19 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 1612-1620 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A population balance model presented describes simultaneous coagulation and fragmentation during shear-induced flocculation. Given sufficient time, a floc-size distribution reaches steady state that reflects the balance between coagulation and fragmentation. The model agrees with experimental data for the evolution of the average floc size. Higher shear shifts the steady-state size distribution to smaller sizes. When the steady-state size distributions obtained at various shear rates are scaled with the average floc size, however, they collapse onto a single line. This indicates that the steady-state floc-size distribution is self-preserving with respect to fluid shear. This distribution is universal for the employed coagulation and fragmentation rates provided that less than 5% (by number) of the particles remain unflocculated. This result is supported with experimental data on shear-induced flocculation of polystyrene particles, although a detailed quantitative comparison is limited by the irregular structure of the flocs.
    Additional Material: 6 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 2635-2644 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The significance of the statistical character of wall-cooled packed-bed reactors was studied by measuring angular temperature variations, which result from the random nature of the packing. These are neglected in present-day mathematical models designed to describe the reactor behavior. The amplitude of these variations was determined experimentally as a function of the mass flux and the position in the tube, under conditions of heat transfer as well as of reaction. Angular variations are significant whenever radial temperature gradients are large.Different methods used to average observed variations were surveyed. For the system presented, the angular variations have only a limited influence on the reaction rates if the angular averaged temperature is used. Thus, a two-dimensional deterministic continuum model can be used, notwithstanding the statistical character of the packed bed.
    Additional Material: 14 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 2668-2682 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A bioartificial pancreas, consisting of immobilized islets encapsulated within hollow fibers, is investigated as an alternative treatment for insulin-dependent diabetes. A mathematical model is developed to determine whether this configuration of the bioartificial pancreas can yield an insulin response to a glucose challenge with the appropriate dynamics in diabetic humans. The model consists of the 2-D mass-conservation equations for glucose and insulin within the hollow fiber and capillaries. The equations contain terms for insulin-production kinetics by porcine islets and glucose-consumption kinetics. The boundary conditions account for transport resistances of the fiber membrane, the tissue surrounding the implant, and a thin film within the capillaries. The equations are coupled to a pharmacokinetic model of the circulatory system. The calculations show that an optimized design with this configuration will be feasible for human use and requires a total volume of 4.6 mL to reach the target insulin concentration in the bloodstream following a glucose challenge. The parameters and processes controlling the system performance are discussed.
    Additional Material: 13 Ill.
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