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  • Biochemistry and Biotechnology  (46)
  • Chemical Engineering  (37)
  • EARTH RESOURCES AND REMOTE SENSING
  • ENERGY PRODUCTION AND CONVERSION
  • GEOPHYSICS
  • 1995-1999  (83)
  • 1980-1984
  • 1975-1979
  • 1996  (83)
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  • 1995-1999  (83)
  • 1980-1984
  • 1975-1979
Year
  • 1
    Electronic Resource
    Electronic Resource
    Chaotic mixing of two similar fluids in the presence of a third dissimilar fluid (1996)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 3301-3309 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Two-dimensional chaotic mixing of similar Newtonian fluids in the presence of an advected dissimilar minor phase fluid body with specified size, interfacial tension, and viscosity ratio was numerically investigated. Interfacial tension was sufficiently high to allow only small deformations in the dissimilar minor phase body. Mixing was confined to a rectangular cavity with periodically driven upper and lower surfaces. Regions of regular motion (i.e., islands) of comparable size to the minor phase body were eventually destroyed or replaced by the minor phase body. Islands persisted for longer times when the initial separation distance between the minor phase body and island was large or when the viscosity ratio was small. When interfacial tension was small enough to deform the minor phase body more readily, islands showed little indication of instability. Results suggest opportunities for improving mixing uniformity in practical processes and disclose how interactions between dissimilar fluids affect mixing.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690421202
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  • 2
    Electronic Resource
    Electronic Resource
    Perturbation analysis of Thomas and Windle's model of Case II transport (1996)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 2025-2035 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Thomas and Windle's model of Case II transport is analyzed for a semiinfinite medium by a singular perturbation technique. Two adjacent boundary layers separate equilibrated and dry regions. A thin boundary layer of width ∼ O(M-1/2/ln M), where M (≫1) dictates how rapidly the mixture's viscosity decays with liquid concentration, sits next to the equilibrated outer left region. Here, quasi-steady diffusion balances relaxation. A thicker intermediate layer of width ∼ O(M-1/2) separates the lefthand boundary layer and the dry outer region on the right, where both relaxation and unsteady diffusion participate in the transport. Matching the solutions at leading order specifies the moving front's speed, v: v ∼ M1/2. The analysis indicates that relaxation significantly affects the nearly dry region just ahead of the moving front. This disagrees with the widely accepted view that ordinary diffusion dominates in the nearly dry righthand region. Approximating that ordinary diffusion dominates in this region leads to a stepexponential concentration profile at the front and a simple analytical solution for the front speed, v with the correct M scaling. This approximate result accurately predicts the values of v determined by direct numerical solutions.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690420723
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  • 3
    Electronic Resource
    Electronic Resource
    Inherent safety, health, and environmental (SHE) reviews (1996)
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 15 (1996), S. 48-51 
    Details
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Implementing an Inherent SHE Review process is under way at the Exxon Chemical Company and progress is being made in the pursuit of inherently safer, healtheir, and environmentally friendly processes. The review integrates well with the company's systems for process safety management, new product development, and project execution. In addition, the Inherent SHE Review process has been quite helpful in educating the organization with regard to the appoprite use of the laboratory in developing reactive chemistry understanding during product and process development. Another benefit of the Inherent SHE Review process is the proactive involvement of industrial hygiene early in the product development and project execution processes.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/prs.680150112
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  • 4
    Electronic Resource
    Electronic Resource
    Sparging and agitation-induced injury of cultured animals cells: Do cell-to-bubble interactions in the bulk liquid injure cells? (1996)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 51 (1996), S. 399-409 
    Details
    ISSN: 0006-3592
    Keywords: cell damage ; cell culture ; bubble aeration ; agitation ; bubble coalescence and breakup ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: It has been established that the forces resulting from bubbles rupturing at the free air (gas)/liquid surface injure animal cells in agitated and/or sparged bioreactors. Although it has been suggested that bubble coalescence and breakup within agitated and sparged bioreactors (i.e., away from the free liquid surface) can be a source of cell injury as well, the evidence has been indirect. We have carried out experiments to examine this issue. The free air/liquid surface in a sparged and agitated bioractor was eliminated by completely filling the 2-L reactor and allowing sparged bubbles to escape through an outlet tube. Two identical bioreactors were run in parallel to make comparisons between cultures that were oxygenated via direct air sparging and the control culture in which silicone tubing was used for bubble-free oxygenation. Thus, cell damage from cell-to-bubble interactions due to processes (bubble coalescence and breakup) occurring in the bulk liquid could be isolated by eliminating damage due to bubbles rupturing at the free air/liquid surface of the bioreactor. We found that Chinese hamster ovary (CHO) cells grown in medium that does not contain shear-protecting additives can be agitated at rates up to 600 rpm without being damaged extensively by cell-to bubble interactions in the bulk of the bioreactor. We verified this using both batch and high-density perfusion cultures. We tested two impeller designs (pitched blade and Rushton) and found them not to affect cell damage under similar operational conditions. Sparger location (above vs. below the impeller) had no effect on cell damage at higher agitation rates but may affect the injury process at lower agitation intensities (here, below 250 rpm). In the absence of a headspace, we found less cell damage at higher agitation intensities (400 and 600 rpm), and we suggest that this nonintuitive finding derives from the important effect of bubble size and foam stability on the cell damage process. © 1996 John Wiley & Sons, Inc.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Modulation of the phosphate-starvation response in Escherichia coli by genetic manipulation of the polyphosphate pathways (1996)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 51 (1996), S. 434-438 
    Details
    ISSN: 0006-3592
    Keywords: polyphosphate ; Escherichia coli ; phosphate starvation ; gene expression ; heterologous ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effect of intracellular polyphosphate on the phosphate-starvation response in Escherichia coli was studied by genetically manipulating the intracellular polyphosphate levels and by performing phosphate shifts on the genetically engineered strains. Strains that produced large quantities of polyphosphate and were able to degrade it induced the phosphate-starvation response to a lesser extent than wild-type strains, whereas strains that were unable to degrade a large intracellular polyphosphate pool induced the phosphate-starvation response to a greater extent than wild-type strains. These results have important implications for expression of heterologous genes under control of the phoA promoter. © 1996 John Wiley & Sons, Inc.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Cryocooler development (1995 AIChE Institute Lecture) (1996)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 3202-3211 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Increased demand for cryocoolers for aerospace and terrestrial applications has served as an incentive over the past decade to develop units with specific performance parameters. Since many of these units also require a high degree of reliability, considerable effort has been directed toward meeting this goal. The excellent progress that has been made is summarized, and there is every indication that the use of cryocoolers will expand greatly during the next decade, with a rapid transition from present aerospace/military applications to highly civilian uses in such areas as medicine, electronic transmission, environmental control, energy storage, and transportation.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690421121
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  • 7
    Electronic Resource
    Electronic Resource
    Steady and unsteady computation of impeller-stirred reactors (1996)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 2701-2712 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A general computational approach is presented for numerical modeling of viscous flow in baffled, impeller-stirred-tank reactors. A multiblock, body-fitted grid structure facilitates modeling of various impeller and baffle designs, and a new procedure offers averaged velocity data from a complex 3-D CFD dataset. Impellers are modeled precisely, eliminating the need for inputting experimental velocity data for boundary conditions. The method can be used quickly to obtain extremely detailed flow computations at a fraction of the cost of computing unsteady moving grid solutions. A steady-state computational approach that neglects the relative motion between impeller and baffles yields numerical results comparably accurate to full unsteady computations for laminar flow at a fraction of the time and expense. The approximate steady-state method is used to predict power requirements of a Rushton turbine in laminar flow.An unsteady, moving grid technique provides time-accurate solutions for the flow inside an impeller-stirred reactor with side-wall baffles. These computed results are compared with those using the approximate steady-state method and with experimental measurements. The unsteady, moving grid method uses two different initial conditions: one starting from rest and the other starting from an approximate steady-state solution obtained at the starting position of the impeller relative to the baffles. For unsteady simulations of laminar flow in stirred vessels, the final operating condition can be achieved much more efficiently if the solution obtained from the steady-state procedure is used as an approximate initial condition.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690421002
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  • 8
    Electronic Resource
    Electronic Resource
    Boiling on a straight pin fin (1996)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 2721-2728 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In this study, Multimode boiling on a straight pin is theoretically investigated. Axial steady-state temperature distributions along the fin are numerically evaluated, as well as their linear stability characteristics. When film and transition boiling coexist on the fin surface, or only the transition boiling covers the entire fin, the operation remains stable only if the fin length is less than some critical value. When transition and nucleate boiling coexist on a fin, or the fin is in the three-mode boiling (film + transition + nucleate boiling), the entry of nucleate boiling at the fin tip stabilizes the boiling process. This study on base heat flow and fin efficiency with the stability criteria also suggests a new fin design methodology.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690421004
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  • 9
    Electronic Resource
    Electronic Resource
    Extension of a generalized quartic equation of state to pure polar fluids (1996)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 562-570 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A generalized four-parameter quartic equation of state (EOS) proposed by Shah and coworkers (1992, 1994) was extended to polar fluids. To use the new generalized quartic EOS for polar fluids, only four characteristic properties of the pure compound are required - critical temperature, critical volume, acentric factor, and dipole moment. For nonpolar fluids, the previous equation is recovered and its superior performance for nonpolar fluids is retained. A new set of coefficients for polar fluids for the EOS was determined from multiproperty regressions using literature data for various physical and thermodynamic experimental properties of 30 pure compounds. These regressed coefficients, which are functions of the critical temperature, critical pressure, acentric factor, and the dipole moment of the fluid, were generalized. The accuracy of this equation of state is evaluated with the new set of regressed coefficients to predict thermodynamic properties of pure polar compounds, including vapor pressure, density, residual enthalpy, enthalpy of vaporization, and second virial coefficient. The capability and accuracy of this quartic equation of state are also compared with the well-known Peng-Robinson EOS.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690420225
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  • 10
    Electronic Resource
    Electronic Resource
    Simulation of fluidized beds and other fluid-particle systems using statistical mechanics (1996)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 660-670 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The expansion behavior and structural phenomena of fluid-particle systems was simulated using a method analogous to the Monte Carlo method for molecular systems. Individual particles are moved, and the resulting moves are accepted or declined based on the change in the system's potential energy and the average kinetic energy of the system. Several fluid-particle systems have been successfully predicted with the model including colloidal particle concentration profiles and random packing of uniform spheres. Additionally, predictions of steady-state fluidized-bed expansion characteristics for uniformly sized stainless-steel spheres and narrowly distributed nickel and glass spheres show excellent agreement with the theoretical model used in the simulation and satisfactory agreement with experimental data. Dynamic expansion predictions of both bed height and overall bed structure as a function of time also agree with the experimental data.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690420307
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