ISSN:
0377-0486
Schlagwort(e):
Chemistry
;
Analytical Chemistry and Spectroscopy
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
,
Physik
Notizen:
The separation of the Raman correlation function as a product of independent vibrational and reorientational correlation functions is investigated. The present model is a unification of previous models which treat separately vibrational dephasing and reorientational relaxation within the context of the stochastic approach. It indicates that the so-called product approximation for the Raman correlation function can fail even when the relaxation rate is distinct for vibrational and reorientational relaxations. Application to experimental data for liquid CS2 is presented.
Zusätzliches Material:
6 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/jrs.1250260826
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