ISSN:
1436-2449
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Summary Novel amphiphilic N-alkyl-, N-decenyl-, and N-alkyl-N'-methyl-semicarbazones of maltose and maltotriose with CnH2n+1 alkyl chains and n=8,9,10,11,12,16 were applied as emulsifiers in styrene emulsion polymerization. Surfactant properties, emulsion polymerization, and rheology were examined as a function of amphiphile molecular architectures. Both critical micelle concentration and average polystyrene particle size increased with decreasing alkyl chain length. Using N-methyl-N-[11-(acryloylamino)-undecanoyl]-glucamine comonomer in a starved feed emulsion polymerization process, it was possible to prepare uniform polystyrene latex with glucamide surface.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00423370
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