ISSN:
1435-1528
Keywords:
Viscosity temperature
;
polymer melts
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Abstract Based on the free volume concept and the equation by Doolittle, an empirical equation is offered for the flow activation energy, E *, for polymer melts for the range of over 150°C above glass transition temperature, T g. This E * represents the temperature coefficient of viscosity for the Newtonian region which is also equal to the value measured at constant shear stress for non-Newtonian flow. Data show that the E * of linear polymers approaches a constant value for a temperature range above T g+150°C. Data on 17 polymers are correlated. The proposed equation for this region predicts the E * of polymer melts from the volume expansion coefficient, αl, above T g and also from the T g. Correlations have also been developed between E * and α l and between E * and T g by simplifying the equation by use of the Simha-Boyer expression. A polymer having a lower α l or higher T g generally has a higher E *. However, more satisfactory results are obtained by calculating E * from both α l and T g. The E * calculated is found to agree with measurements within the experimental precision of about ±1 Kcal/mole. The effects of polymer composition, molecular weight, branching and microstructure on E * are also discussed. These factors influence E * in the way in which they effect α l and T g.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00396562
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