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  • Analytical Chemistry and Spectroscopy  (133)
  • GEOPHYSICS  (59)
  • Physics
  • 1995-1999  (192)
  • 1980-1984
  • 1965-1969
  • 1995  (192)
Collection
Keywords
Publisher
Years
  • 1995-1999  (192)
  • 1980-1984
  • 1965-1969
Year
  • 1
    Electronic Resource
    Electronic Resource
    Ionophores: Potential screening via supercritical-fluid chromatography combined with mass spectrometry and tandem mass spectrometry (1995)
    New York, NY : Wiley-Blackwell
    Rapid Communications in Mass Spectrometry 9 (1995), S. 712-716 
    Details
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: A variety of ionophores have been studied by packed column supercritical-fluid chromatography combined with mass spectrometry. One of the ionophores, lasalocid, provided particularly good multiple-reaction monitoring signal-to-noise responses when analysed by tandem mass spectrometry and this approach shows considerable potential for the analysis of this compound in medicated animal feeds. A capillary supercritical-fluid chromatograph has been interfaced to an unmodified benchtop quadrupole mass spectrometer and this combination has enabled the molecular weight determination of the sodium salt of an ionophore.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/rcm.1290090816
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    EXAFS and FTIR studies on the binding of deoxycholic acid with copper and zinc ions (1995)
    New York, NY [u.a.] : Wiley-Blackwell
    Biospectroscopy 1 (1995), S. 291-296 
    Details
    ISSN: 1075-4261
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Physics
    Notes: Deoxycholic acid is an important physiological bile acid. The binding of bile salts with metal ions has received more attention due to its clinical significance. In this study, a series of copper and zinc deoxycholate complexes were synthesized. EXAFS and FTIR spectroscopic techniques were used for characterization. The results indicated that both the carboxyl and hydroxyl groups of deoxycholic acid are binding to the Cu (or Zn) ion to form a new complex. There are six oxygen atoms surrounding the metal ion with the average bond lengths of Cu-O and Zn-O are 1.95 and 2.06 Å respectively. © 1995 John Wiley & Sons, Inc.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bspy.350010407
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  • 3
    Electronic Resource
    Electronic Resource
    The Townes and Dailey approach to the interpretation of NQR parameters in the light of non-empirical calculations. Three-membered rings (1995)
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 33 (1995), S. 761-766 
    Details
    ISSN: 0749-1581
    Keywords: non-empirical calculations ; NQR parameters ; Townes and Dailey theory ; three-membered rings ; LMO approach ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The nuclear and electronic contributions to the EFG tensor components eqii at 14N, 17O, 33S and 35Cl nuclei in aziridine, methylaziridine, chloroaziridine, oxirane and thiirane were determined. The nuclear contributions were calculated within classical representations, while electronic contributions were calculated non-empirically using a 6-31G* basis set within the framework of the LMO approach. On the basis of the analysis of the contributions to the EFG tensor components from definite bond and lone-pair orbitals, the main concepts of the Townes and Dailey approach were tested.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/mrc.1260331002
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  • 4
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    Observations in the vicinity of substorm onset: Implications for the substrom process (1995)
    In:  Other Sources
    Details
    Publication Date: 2019-07-13
    Description: Multi-instrument data sets from the ground and satellites at both low and high altitude have provided new results concerning substorm onset and its source region in the magnetosphere. Twenty-six out of 37 substorm onset events showed evidence of azimuthally spaced auroral forms (AAFs) prior to the explosive poleward motion associated with optical substorm onset. AAFs can span 8 hours of local time prior to onset and generally propagate eastward in the morning sector. Onset itself is, however, more localized spanning only about 1 hour local time. AAF onset occur during time periods when the solar wind pressure is relatively high. AAFs brighten in conjunction with substorm onset leading to the conclusion that they are a growth phase activity casually related to substorm onset. Precursor activity associated with these AAFs is also seen near geosynchronous orbit altitude and examples show the relationship between the various instrumental definitions of substorm onset. The implied mode number (30 to 135) derived from this work is inconsistent with cavity mode resonances but is consistent with a modified flute/ballooning instability which requires azimuthal pressure gradients. The extended source region and the distance to the open-closed field line region constrain reconnection theory and local mechanisms for substorm onset. It is demonstrated that multiple onset substorms can exist for which localized dipolarizations and the Pi 2 occur simultaneously with tail stretching existing elsewhere. These pseudobreakups can be initiated by auroral streamers which originate at the most poleward set of arc systems and drift to the more equatorward main UV oval. Observations are presented of these AAFs in conjunction with low- and high-altitutde particle and magnetic field data. These place the activations at the interface between dipolar and taillike field lines probably near the peak in the cross-tail current. These onsets are put in the context of a new scenario for substorm morphology which employs individual modules which operate independently or couple together. This allows particular substorm events to be more accurately described and investigated.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 100; A5; p. 7937-7969
    Format: text
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    NASA TECHNICAL REPORTS
  • 5
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    Preliminary results from the Sprites94 aircraft campaign: 1. Red sprites (1995)
    In:  Other Sources
    Details
    Publication Date: 2019-07-13
    Description: The dual jet aircraft Sprites94 campaign yielded the first color imagery and unambiguously triangulated physical dimensions and heights of upper atmospheric optical emissions associated with thunderstorm systems. Low light level television images, in both color and in black and white (B/W), obtained during the campaign show that there are at least two distinctively different types of optical emissions spanning part or all of the distance between the anvil tops and the ionosphere. The first of these emissions, dubbed 'sprites' after their elusive nature, are luminous structures of brief (less than 16 ms) duration with a red main body that typically spans the latitude range 50-90 km, and possessing lateral dimensions of 5-30 km. Faint bluish tendrils often extend downward from the main body of sprites, occasionally appearing to reach cloud tops near 20 km. In this paper the principal characteristics of red sprites as observed during the Sprites94 campaign are described. The second distinctive type of emissions, 'blue jets,' are described in a companion paper (Wescott et al., this issue).
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters (ISSN 0094-8276); 22; 10; p. 1205-1208
    Format: text
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  • 6
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    A description of the solar wind-magnetosphere coupling based on nonlinear filters (1995)
    In:  Other Sources
    Details
    Publication Date: 2011-08-24
    Description: A nonlinear filtering method is introduced for the study of the solar wind -- magnetosphere coupling and related to earlier linear techniques. The filters are derived from the magnetospheric state, a representation of the magnetospheric conditions in terms of a few global variables, here the auroral electrojet indices. The filters also couple to the input, a representation of the solar wind variables, here the rectified electric field. Filter-based iterative prediction of the indices has been obtained for up to 20 hours. The prediction is stable with respect to perturbations in the initial magnetospheric state; these decrease exponentially at the rate of 30/min. The performance of the method is examined for a wide range of parameters and is superior to that of other linear and nonlinear techniques. In the magnetospheric state representation the coupling is modeled as a small number of nonlinear equations under a time-dependent input.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 100; A3; p. 3495-3512
    Format: text
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  • 7
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    Preliminary results from the Sprites94 aircraft campaign: 2. Blue jets (1995)
    In:  Other Sources
    Details
    Publication Date: 2011-08-24
    Description: Initial observations of a newly documented type of optical emission above thunderstorms are reported. 'Blue jets', or narrowly collimated beams of blue light that appear to propagate upwards from the tops of thunderstorms, were recorded on B/W and color video cameras for the first time during the Sprites94 aircraft campaign, June-July, 1994. The jets appear to propagate upward at speeds of about 100 km/s and reach terminal altitudes of 40-50 m. Fifty six examples were recorded during a 22 minute interval during a storm over Arkansas. We examine some possible mechanisms, but have no satisfactory theory of this phenomenon.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters (ISSN 0094-8276); 22; 10; p. 1209-1212
    Format: text
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  • 8
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    The double oval UV auroral distribution. 2: The most poleward arc system and the dynamics of the magnetotail (1995)
    In:  Other Sources
    Details
    Publication Date: 2019-07-13
    Description: The poleward arc system of a double oval distribution is shown to activate at the end of the optical expansion phase signifying the beginning of substorm recovery. The velocity dispersed ion signature (VDIS) can exist coincident with this discrete aurora developing on the most poleward oval. Although the VDIS is usually associated with ion beams in the plasma sheet boundary layer, it is demonstrated that the ionospheric signature is not beamlike but distributed in pitch angle. At the time when the double oval begins to form, the magnetic field in the magnetotail lobe becomes less flared and can show Pc 5 period oscillations. Similar pulsations also exist in the ionosphere associated with the most poleward oval and with stationary surge formation. Theoretical considerations link this phenomenon with a wave source tailward of x(sub GSE) = -30R(sub E) and fast mode evanescent waves propagating earthward in the tail lobe region. In this case the magnetotail appears to act like a waveguide and the plasma sheet boundary layer as a resonance region. This implies that the coupling of this fast mode waves is with the plasma sheet boundary layer and not with dipolar like field lines. The implications of this for the reconnection model of substorms are discussed.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 100; A7; p. 12,093-12,102
    Format: text
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    NASA TECHNICAL REPORTS
  • 9
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    The double oval UV auroral distribution. 1: Implications for the mapping of auroral arcs (1995)
    In:  Other Sources
    Details
    Publication Date: 2019-07-13
    Description: During the later stages of the auroral substorm the luminosity distribution frequently resembles a double oval, one oval lying poleward of the normal or main UV auroral oval. We interpret the double oval morphology as being due to the plasma sheet boundary layer becoming active in the later stages of the substorm process. If the disturbance engulfs the nightside low-latitude boundary layers, then the double oval configuration extends into the dayside ionospheric region. The main UV oval is associated with the inner portion of the central plasma sheet and can rapidly change its auroral character from being diffuse to discrete. This transition is associated with the substorm process and is fundamental to understanding the near-Earth character of substorm onset. On the other hand, the poleward arc system in the nightside ionosphere occurs adjacent to or near the open-closed field line boundary. This system activates at the end of the optical expansion phase and is a part of the recovery phase configuration in substorms where it occurs. These two source regions for nightside discrete auroral arcs are important in resolving the controversy concerning the mapping of arcs to the magnetosphere. The dayside extension of this double oval configuration is also investigated and shows particle signatures which differ considerably from those on the nightside giving clues to the magnetospheric source regions of the aurora in the two local time sectors. Near-Earth substorm onsets are shown to be coupled to processes occurring much further tailward and indicate the importance of understanding the temporal development of features within the double oval. Using 'variance images,' a new technqiue for the investigation of these dynamics is outlined.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 100; A7; p. 12,075-12,092
    Format: text
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  • 10
    Electronic Resource
    Electronic Resource
    Copper bilirubinate and black pigment gallstone (1995)
    New York, NY [u.a.] : Wiley-Blackwell
    Biospectroscopy 1 (1995), S. 149-156 
    Details
    ISSN: 1075-4261
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Physics
    Notes: A series of copper bilirubinate complexes (CuBR) was synthesized in solution and in solid state to mimic the black color of the black-pigment gallstone and to explore the formation mechanism of the gallstonein vitro. The variation of the copper contents of these samples indicated that CuBR also exhibits nonstoichiometric characteristics from the FTIR study, i.e., both the so-called acid and neutral copper complex moieties exist in CuBR. The NH groups in pyrrole and lactam groups of bilirubin (H2BR) are binding to the copper ions. An EPR study demonstrates the generation of free radicals and the variation of its electronic structure and conjugation system in the skeleton of H2BR molecule during complex formation. A polymer of CuBR may form through the reaction of H2BR with copper ions. © 1995 John Wiley & Sons, Inc.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bspy.350010209
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