ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The crystal structure of the title compound, (2,2′-bipyridyl-κ2N,N′)(tetraallyl 3,3,3′,3′-tetramethyl-1,1′-bicyclopropane-1,1′,2,2′-tetracarboxylato-κ2C2,C2′)palladium(II), [Pd(C26H32O8)(C10H8N2)], is disordered above 194 K. A doubling of the unit cell is observed on cooling. The structure at 143 K contains two ordered molecules related by a pseudo-translation vector of approximately (0.44,0.00,0.50) or a pseudo-inversion center at approximately (0.22,0.00,0.25). Weak intermolecular C—H...O interactions are enhanced in the low-temperature structure.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270100006193
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