ISSN:
0025-116X
Schlagwort(e):
Chemistry
;
Polymer and Materials Science
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
,
Physik
Notizen:
Six new acetylene-terminated (AT) oligomers were synthesized by reaction of 3-ethynylbenzoyl chloride and 4-ethynylbenzoyl chloride with three aromatic diamines containing four aromatic rings. The functionalization led quantitatively to AT oligomeric diamides of well defined composition, as confirmed by IR, 1H NMR and 13C NMR spectroscopy. The materials exhibited comparatively high melting points, over 200°C; thus, heating promoted curing before melting or simultaneously with melting, with the only exception of one sample that could be isolated in the amorphous state. Heating at 325°C led to insoluble cured materials, with excellent thermal resistance and glass transition temperatures Tg around 300°C.
Zusätzliches Material:
8 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/macp.1993.021940318
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