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  • Sand  (1)
  • Supercritical carbon dioxide  (1)
  • copolyester  (1)
  • Wiley-Blackwell  (2)
  • American Association for the Advancement of Science
  • American Chemical Society (ACS)
  • Oxford University Press
  • 1990-1994  (2)
  • 1993  (2)
Collection
Publisher
  • Wiley-Blackwell  (2)
  • American Association for the Advancement of Science
  • American Chemical Society (ACS)
  • Oxford University Press
Years
  • 1990-1994  (2)
Year
  • 1993  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 16 (1993), S. 713-716 
    ISSN: 0935-6304
    Keywords: SFE ; Supercritical carbon dioxide ; Sand ; Test mixture ; Solvent trapping ; Solvent mixtures ; Trapping efficiency ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A polarity test mix consisting of acetophenone, N, N-dimethylaniline, naphthalene, decanoic acid, 2-naphthol, and n-tetracosane was spiked onto sand, and extracted with supercritical carbon dioxide, to evaluate the collection efficiency of various solvents and solvent mixtures. Nine single collection solvent systems and four mixed collection solvent systems were studied. When one-component collection solvents were employed, quantitative (above 90%) recovery of all analytes was not possible. With mixed collection solvents, recoveries of 90% or better with all analytes studied were possible.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 31 (1993), S. 1067-1073 
    ISSN: 0887-6266
    Keywords: polyarylate ; copolyester ; liquid crystal ; transesterfication ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The miscibility has been investigated for binary blends of a polyarylate (PAr) with a liquid crystalline copolyester of p-hydroxybenzoate and ethylene terephthalate units in a 6/4 molar ratio (PET/PHB). The binary blends were prepared by solution precipitation. The transitions of the PET/PHB have been measured with a rheometrics dynamic spectrometer. The phases in blends have been studied with a differential scanning calorimeter, by ther-mogravimetry and with a polarizing optical microscope. The blends exhibit two glass transitions (Tgs) over the composition range 10-90 wt %. The amorphous PET phase from the PET-PHB is found to be partially miscible with PAr, which leads to a decrease of the PAr Tg. The amount of this partially miscible portion of PET has been estimated by the Couch-man equation. On heat treatment of the blends at 250 to 300°C, transesterficiation takes place, as judged by the shift of the higher of the two Tgs. © 1993 John Wiley & Sons, Inc.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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