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  • Analytical Chemistry and Spectroscopy  (135)
  • Chemical Engineering  (77)
  • GENERAL
  • Organic Chemistry
  • 1990-1994  (249)
  • 1960-1964
  • 1955-1959
  • 1925-1929
  • 1993  (249)
Collection
Keywords
Publisher
Years
  • 1990-1994  (249)
  • 1960-1964
  • 1955-1959
  • 1925-1929
Year
  • 1
    Electronic Resource
    Electronic Resource
    Simultaneous determination of rare earths by x-ray fluorescence spectrometry using a fundamental parameters method (1993)
    New York, NY [u.a.] : Wiley-Blackwell
    X-Ray Spectrometry 22 (1993), S. 362-367 
    Details
    ISSN: 0049-8246
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Concentrates extracted from a lateritic mineral deposit were analysed for their rare earth (RE) content by energy-dispersive x-ray fluorescence (XRF) spectrometry. The L emission lines of the lanthanides were excited with the 22.1 keV Ag K radiation from an annular Cd-109 radioisotope source. The problem of the extensive overlap of the L lines were solved by the AXIL program for deconvolution of XRF spectra. Individual REs were quantified by preparing semi-transparent pellets of the concentrate with starch which served as dilutant and binder. This allowed correction for sample absorption with the light matrix program of the QXAS analysis package based on the fundamental parameter method. The method allowed the simultaneous determination of 12 rare earths contained in the sample, with a reproducibility of 2.0-29% and accuracy in the range 1.5-24% relative error without the use of standard materials. Detection limits achieved were in the range of 340 ppm for the heavy REs and 4000 ppm for the light REs.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/xrs.1300220508
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  • 2
    Electronic Resource
    Electronic Resource
    Skeletal vibrational spectra of LAuCl3 complexes with heterocyclic nitrogen donors (1993)
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 24 (1993), S. 233-235 
    Details
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The low-frequency Raman and infrared spectra of a series of gold(III) chloride complexes of the type of LAuCl3 (where L is thiazole, oxazole and their derivatives) were studied. The skeletal gold-chlorine and the gold-ligand vibrations were assigned.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jrs.1250240409
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  • 3
    Electronic Resource
    Electronic Resource
    Muricatetrocins A and B and Gigantetrocin B: Three New Cytotoxic Monotetrahydrofuran-Ring Acetogenins from Annona muricata (1993)
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 76 (1993), S. 2433-2444 
    Details
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Extracts from the seeds of Annona muricata yielded three new Annonaceous acetogenins: muricatetrocin A (= (5S)-3-{(2R)-2-hydroxy-9-{(2R,5S)-tetrahydro-5-[(1S,4S,5S)-1,4,5-trihydroxyheptadecyl]furan-2-yl}nonyl}-5-methylfuran-2(5H)-one; 1), muricatetrocin B (= (5S)-{(2R)-2-hydroxy-9-{(2S,5S)-tetrahydro-5-[(1S,4S,5S)-1,4,5-trihydroxyheptadecyl]furan-2-yl}nonyl}-5-methylfuran-2(5H)-one; 2), and gigantetrocin B (= (5S)-3-{(2R)-2-hydroxy-7-{(2S,5S)-tetrahydro-5-[(1S,4R,5R)-1,4,5-trihydroxynonadecyl]furan-2-yl}heptyl}-5-methyl-furan-2(5H)-one; 3). Their C-skeletons were deduced by mass spectrometry. Configurations were determined by 1H-NMR of ketal derivatives and 2D-NMR experiments utilizing Mosher esters. A previously described compound, gigantetrocin A (= (5S)-3-{(2R)-2-hydroxy-7-{(2S,5S)-tetrahydro-5-[(1S,4S,5S)-1,4,5-trihydroxynonadecyl]furan-2-yl}heptyl}-5-methylfuran-2-(5H)one; 4), was also isolated and is new to this species. Compounds 1-4 were all selectively cytotoxic for the HT-29 human colon-tumor cell line with potencies at least 10 times that of adriamycin.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/hlca.19930760703
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  • 4
    Electronic Resource
    Electronic Resource
    Use of the Kalman filter for multivariate calibration in a real system and its comparison with CLS and pure component calibration methods (1993)
    New York, NY : Wiley-Blackwell
    Journal of Chemometrics 7 (1993), S. 267-275 
    Details
    ISSN: 0886-9383
    Keywords: Kalman filter ; Multivariate calibration ; Condition number ; Prediction error ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The usefulness of the Kalman filter as an algorithm for calibration in a real system is shown. Results are compared with classical least squares and pure component calibration. The prediction of four priority pollutant chlorophenols in binary, ternary and quaternary mixtures was also carried out by Kalman filtering. The condition number, standard deviation and prediction error have been employed to choose the most suitable wavelength range. Comparison of the standard error of prediction in the validation set shows significant differences between the evaluated chlorophenols, the best results being obtained with Kalman multivariate calibration.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cem.1180070405
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  • 5
    Electronic Resource
    Electronic Resource
    Cosolvent interactions in supercritical fluid solutions (1993)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 39 (1993), S. 235-248 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The addition of cosolvents to supercritical fluid (SCF) solvents can have large effects on solubilities, giving engineers the ability to tailor loadings and selectivities of solutes for difficult separations. It is necessary to have a better understanding of the special intermolecular interactions that occur in SCF solutions to predict the effects of cosolvents. We use a SCF chromatographic technique to acquire a database of cosolvent effects for a variety of cosolvents and solutes; examination of the cosolvent effects shows evidence of hydrogen bonding, charge transfer complex formation, and dipole-dipole coupling between solute and cosolvent molecules. SCF solvents, carbon dioxide, ethane, and fluoroform, are compared, and then the use of the chromatograph to measure solubilities is discussed.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690390206
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  • 6
    Electronic Resource
    Electronic Resource
    Mean velocity and turbulence fields inside a β=0.50 orifice flowmeter (1993)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 39 (1993), S. 745-756 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The flow field inside an orifice flowmeter with a beta ratio of 0.50 operating at a Reynolds number of 91,100 has been studied using a three-color, 3-D laser Doppler anemometer system. Mean velocity measurements show large radial velocities leading into the orifice, the fluid separating from the orifice plate at the throat, the presence of a vena contracta farther downstream, flow reattachment to the pipe wall 5.3 pipe radii (R) downstream, the presence of a small upstream recirculation zone, and both a primary and secondary recirculation zone downstream of the orifice plate. The static wall pressure distribution attains a minimum pressure at 1.5 R, which does not coincide with the location of the vena contracta (0.75 R). Distributions of the entire Reynolds stress tensor are presented along with calculated values of turbulence kinetic energy, turbulence kinetic energy production, vorticity, and turbulence induced accelerations. These data are analyzed to interpret the complex turbulent flow field.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690390503
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  • 7
    Electronic Resource
    Electronic Resource
    Trapping efficiencies of various collection solvents after supercritical fluid extraction (1993)
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 16 (1993), S. 713-716 
    Details
    ISSN: 0935-6304
    Keywords: SFE ; Supercritical carbon dioxide ; Sand ; Test mixture ; Solvent trapping ; Solvent mixtures ; Trapping efficiency ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A polarity test mix consisting of acetophenone, N, N-dimethylaniline, naphthalene, decanoic acid, 2-naphthol, and n-tetracosane was spiked onto sand, and extracted with supercritical carbon dioxide, to evaluate the collection efficiency of various solvents and solvent mixtures. Nine single collection solvent systems and four mixed collection solvent systems were studied. When one-component collection solvents were employed, quantitative (above 90%) recovery of all analytes was not possible. With mixed collection solvents, recoveries of 90% or better with all analytes studied were possible.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jhrc.1240161208
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  • 8
    Electronic Resource
    Electronic Resource
    Reactions of propene and cyclopropane radical cations with neutral ethylene (1993)
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 28 (1993), S. 185-192 
    Details
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The gas-phase reactions of propene and cyclopropane radical cations with neutral ethylene were investigated by using Fourier transform, chemical ionization and tandem mass spectrometries. Both reactions form covalent C5H10 adduct ions. The adduct ions are hypothesized to form initially as distonic radical cations that isomerize via a substituted cyclopropane intermediate and are detected as the most stable C5H10 isomer, the 2-methylbut-2-ene radical cation. The rate constant for each reaction is approximately 20% of the theoretical collision rate, indicating that product ions are formed in one out of every five collisions of the C3H6 radical cations with neutral C2H4.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/oms.1210280309
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  • 9
    Electronic Resource
    Electronic Resource
    Dielectric characterization of water sorption in epoxy resin matrices (1993)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 33 (1993), S. 75-82 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Water sorption in epoxy based materials was analyzed by dielectric spectroscopy using remote sensors. A method to determine diffusion coefficients from the changes in permittivity during water absorption is proposed and was verified experimentally by comparison with standard water gain measurements. Although the technique is limited by electrode polarization phenomena, it is sensitive to the presence of water molecules and is capable of detecting different levels of water concentration as a function of frequency. The utilization of remote sensors demonstrated the capability of dielectric analysis to be applied both in the laboratory environment, and on a larger scale, as a nondestructive technique for monitoring environmental changes in actual polymer matrix composite parts.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760330204
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  • 10
    Electronic Resource
    Electronic Resource
    Semi-interpenetrating polymer networks composed of poly(ethylene terephthalate) and castor oil: Synthesis, structure, and properties (1993)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 33 (1993), S. 913-922 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Semi-interpenetrating networks have been produced from castor oil and poly(ethylene terephthalate) (PET). Bond interchange between PET and castor oil plays a major role in the development of initial miscibility, also affecting morphology and chemical structure. Microheterogeneous morphology is developed for materials of intermediate composition, which have much greater toughness than the polymers from which they were made.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760331408
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