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  • Chemistry  (3)
  • CYBERNETICS
  • Computer Systems
  • 1990-1994  (3)
  • 1970-1974
  • 1935-1939
  • 1993  (3)
  • 1
    Electronic Resource
    Electronic Resource
    Thermal stability, morphological, dielectric, and conductivity characteristics of pyrrole modified poly-N-vinyl carbazole (1993)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 49 (1993), S. 2189-2196 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: N-vinyl-Carbazole (NVC) has been polymerized in the presence of pyrrole (PY) by anhydrous ferric chloride. The copolymer has been characterized by IR Spectroscopy. Thermal stability of P(PY-NVC) is intermediate between that of PNVC and PPY, respectively. DSC reveals a single glass transition break at 180-200°C for P(PY-NVC), which is higher than the Tg for polypyrrole (∼ 165°C), but is lower than that for PNVC (∼ 227°C). The XRD analysis reveals PPY to be totally amorphous and shows the percent crystallinity for P(PY-NVC) to be less than that of PNVC. Dielectric constants of the polymers follow the trend: PPY 〉 P(PY-NVC) 〉 PNVC, and fall sharply with the applied frequency to a limiting value. The polymers are characterized by a broad dielectric relaxation. DC conductivity is dependent on temperature and FeCl3/polymer mole ratio and at a particular temperature follows the trend: PPY 〉 P(PY-NVC) 〉 PNVC. © 1993 John Wiley & Sons, Inc.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1993.070491215
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  • 2
    Electronic Resource
    Electronic Resource
    Thermal characteristics of iron(III), cobalt(II), and copper(II) complexes of dipyridylamine anchored on polystyrene-divinylbenzene copolymer (1993)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 50 (1993), S. 1485-1492 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Polystyrene-divinylbenzene (PS-DVB) (partially chloromethylated) has been modified by anchoring dipyridylamine (DPA) followed by subsequent complexation with Fe(III), Co(II), and Cu(II). Analytical and spectroscopic evidence has been presented to confirm the attachment of the metal-dipyridyl complex on the PS-DVB matrix. All the metal-loaded polymers exhibit appreciable improvement in thermal stability relative to the base polymer, the initial decomposition temperature and stability order being PS-DVB-DPA-Cu(315°C) 〉 PS-DVB-DPA-Fe(II) (310°C) 〉 PS-DVB-DPA-Co (300°C) 〉 PS-DVB-DPA (280°C) = PS-DVB.DTA studies reveal exothermic peaks between 300 and 380°C, 420 and 440°C, and 500 and 700°C, which are ascribable to the exothermic cleavage of the PS-DVB-DPA matrix. The glass transition temperatures of the modified polymers do not reveal any characteristic difference from the corresponding value for the base polymer. © 1993 John Wiley & Sons, Inc.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1993.070500901
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  • 3
    Electronic Resource
    Electronic Resource
    Phenomenological model for the unified studies of different physical properties of polymers (1993)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 207 (1993), S. 9-21 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Es wird ein phänomenologisches Modell vorgestellt, mit dem sich das Entstehen starker Anisotropien der physikalischen Eigenschaften semikristalliner Polymerer nach einachsigem Verstrecken beschreiben 1äßt. Dieses Modell führt die Temperatur als expliziten Parameter in die Orientierungsfunktion ein. Es enthält zwei frei wählbare Parameter, die für jedes Polymere durch Anpassen der experimentellen Daten der Doppelbrechung als Funktion des Verstreckverhältnisses bei einer bestimmten Temperatur ermittelt werden konnen. Die berechneten Werte für Elastizitätsmodul, thermische Leitfähigkeit und Expansibilität parallel und senkrecht zur Streckrichtung stimmen in einem wäiten Bereich des Verstreckverhältnisses und der Temperatur mit den experimentellen Ergebnissen gut überein.
    Notes: A phenomenological model has been proposed to understand the development of strong anisotropy in physical properties of semicrystalline polymers on uniaxial drawing. The proposed model introduces temperature as an explicit parameter in the orientation function. The model contains two free parameters for each polymer which can be evaluated by fitting the experimental data on birefringence versus draw ratio at a particular temperature. The calculated values of elastic moduli, thermal conductivity and expansibility along and perpendicular to the drawing direction over the entire range of draw ratio and a wide range of temperature are in good agreement with experimental values.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/apmc.1993.052070102
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