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    Electronic Resource
    Electronic Resource
    Kinetics and mechanism of oxidation of aspartic acid by bismuth(V) in HClO4-HF medium (1992)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 24 (1992), S. 963-971 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The kinetics of oxidation of Aspartic acid by bismuth(V) studied in HClO4-HF mixture iodometrically exhibit complex dependence with respect to aspartic acid (AA). The rate law (i) accounts for all the experimental observations. where [Bi(V)] and [AA] are the gross analytical concentration of all fluorobismuth(V) species and the equilibrium concentration of aspartic acid, respectively. The oxidation product of the amino acid was identified to be an aldehyde. HF and F- do not affect the rate of the reaction. © John Wiley & Sons, Inc.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550241106
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