ISSN:
0021-8995
Schlagwort(e):
Chemistry
;
Polymer and Materials Science
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
,
Maschinenbau
,
Physik
Notizen:
Various azobenzene derivatives and polymers were attempted as materials for thin composite films containing a polymer, a liquid crystal, and lithium perchlorate which can undergo ionic-conductivity switching induced by light or heat. Poly(vinyl chloride) -based composite films containing enantiotropic azobenzene liquid crystals 1, exhibited significant ionicconductivity change based on thermo- and photoinduced phase transitions of 1, the temperature dependence on the ionic conductivity reflecting the enantiotropic phase transition behavior of the liquid crystals. Marked, reversible ionic-conductivity switching on alternating irradiation of UV and visible lights was attained with the composite films containing 1, especially 1 (n = 12). Incorporation of monotropic liquid crystals 3 to the composite films allowed bistability in the temperature dependence on the ionic conductivity. Employment of a polycarbonate resin and poly(methyl methacrylate) as the polymer material of the composite films gave similar ionic-conductivity changes to the poly(vinyl chloride) composite films, whereas polyethyleneoxide brought about some different results in the photoinduced ionic-conductivity change.
Zusätzliches Material:
10 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/app.1991.070430704
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