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  • AERODYNAMICS  (99)
  • Chemical Engineering  (77)
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  • 1990-1994  (179)
  • 1965-1969
  • 1955-1959
  • 1991  (179)
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  • 1990-1994  (179)
  • 1965-1969
  • 1955-1959
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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 37 (1991), S. 1895-1899 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 37 (1991), S. 1900-1903 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 31 (1991), S. 592-595 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Reinforced plastics based on poly(cyclohexanedimethylene terephthalate) (PCT) are excellent for electrical and electronic applications, particularly in the manufacture of electrical connectors. PCT offers a high heat deflection temperature, low cost, and relative ease of processing. For the injection molding process, stability of the melt is an important consideration, especially for materials with high melting points such as PCT. The combination of the polyester resin with flame retardant additives, processing aids, and thermal stabilizers results in a number of competing reactions which can change the molecular weight and molecular-weight distribution (MWD) of the base polymer in the composite. Typical analytical techniques such as melt or dilute solution viscosity do not give adequate means of monitoring these changes so as to allow the polymer chemist to determine the effects of various additives on MWD. Size-exclusion chromatography (SEC), by virtue of providing information on the entire MWD, was found suitable to study molecular-weight changes in the melt due to both branching and chain cleavage, even when both phenomena occur simultaneously. Changes in the MWD over time at processing temperatures can be used to determine kinetic parameters and have been used to optimize PCT additive formulations for best processability and mechanical property retention.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 31 (1991), S. 1665-1669 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The Differential Scanning Calorimetry (DSC) trace for a commercial phenolic resole resin shows two distinct peaks. Assuming that these represent two independent cure reactions results in a kinetic model of the form: \documentclass{article}\pagestyle{empty}\begin{document}$$ \frac{{dx}}{{dt}} = p\kappa _1 \left({1 - x_1} \right)^{n_1} + \left({1 - p} \right)\kappa _2 \left({1 - x_2} \right)^{n_2} $$\end{document} with κi = κio exp(-Bi/T).The Arrhenius parameters were estimated from a plot of ln(β/Tp2) versus 1/Tp. The parameters, p, n1, and n2 were obtained by writing the DSC response predicted by the equation above in terms of a function which contains temperature as the only variable. \documentclass{article}\pagestyle{empty}\begin{document}$$ \dot q = q_{tot} \left[{p\kappa _1 \left({1 - \theta _1 /r_1} \right)^{r_1 - 1} + \left({1 - p} \right)\kappa _2 \left({1 - \theta _2 /2} \right)^{r_2 - 1}} \right] $$\end{document} with \documentclass{article}\pagestyle{empty}\begin{document}$ \theta _i = \left({1/\beta} \right)\int_{T_0}^T {\kappa _i dT \le r_i} $\end{document} dT ≤ ri and ri = 1/(1-ni).Fitting this equation to the DSC response measured at a scan rate of 4°C/min obtains p ≈ 0.66; n1 ≈ 0.55; n2 ≈ 2.2; B1 ≈ 8285; B2 ≈ 7480; κ1 ≈ 1. 12 × 108 s-1; κ2 ≈ 0.99 × 106 S-1.
    Additional Material: 3 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 12 (1991), S. 333-337 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The effect of water absorption on the stress transferability across E-glass fiber/nylon 6 interface has been studied using the embedded single fiber composite technique. The behavior of silane coated fiber and untreated fiber composites after periods of water immersion were compared. The silane coating provided both higher interfacial shear stress transferability and protection from permanent water damage in the interphase region. It was found that water absorption in the nylon matrix reduced the shear stress transferability through plasticization of the matrix, weakening of the interface, and the development of tensile swelling stresses at the phase boundaries. In untreated materials the shear stress transferability was limited by decoupling of the matrix from the broken fiber ends by either interface slippage or local plane strain fracture in the interphase region near the fiber end. In the silane treated materials the shear stress transferability was limited by constrained yielding of the polysiloxane/nylon interphase at the fiber end, thus indicating plasticization of the matrix was the primary factor. After 20 days of water immersion, there was permanent deterioration of stress transferability in the untreated samples, but very little permanent damage in the treated samples.
    Additional Material: 3 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 12 (1991), S. 391-403 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The primary goal of this study was to develop 2-D and 3-D computer simulation schemes for the mold filling processes of structural reaction injection molding (SRIM) and resin transfer molding (RTM) under isothermal conditions. The developed computer code was able to simulate the mold filling in molds with complicated geometry, Experiments were also carried out based on flow vitalizations. Experimental results were compared with the numerical simulations.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This work presents the characterization of fibrous reinforcement mats in resin injection molding. The fiber mat characterization involved determining the mat permeability and compressibility. Mold filling experiments were conducted using two or more different fiber types in the mat stack, which created transverse porosity, permeability, and compressibility variations. The effect of these variations was studied by taking flow pressure measurements and observing the progress of the flow front of a non-reactive fluid filling a clear acrylic mold that contained the reinforcement mat stack.
    Additional Material: 12 Ill.
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  • 8
    Publication Date: 2011-08-24
    Description: A development status evaluation is presented for CFD methods applicable to fuselage-integrated scramjet powerplant incorporating hypersonic vehicles; these methods are critically important due to the unavailability of experimental facilities for such elevated Mach number/high-enthalphy conditions. Advancements are required in algorithm robustness and speed, geometric flexibility, and the inclusion of more complete flow physics. The most serious deficiencies lie in turbulence modeling, the lack of complete transition-prediction methods, and combustion modeling.
    Keywords: AERODYNAMICS
    Type: In: Hypersonic flows for reentry problems. Vol. 1 (A93-42576 17-02); p. 55-71.
    Format: text
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  • 9
    Publication Date: 2011-08-19
    Keywords: AERODYNAMICS
    Type: Journal of Aircraft (ISSN 0021-8669); 28; 239-245
    Format: text
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  • 10
    Publication Date: 2019-06-28
    Description: A new two-dimensional approximate Riemann solver has been developed that obtains fluxes on grid faces via wave decomposition. By utilizing information propagation in the velocity-difference directions rather than in the grid-normal directions, this flux function more appropriately interprets and hence more sharply resolves shock and shear waves when they lie oblique to the grid. The model uses five waves to describe the difference in states at a grid face. Two acoustic waves, one shear wave, and one entropy wave propagate in the direction defined by the local velocity difference vector, while the fifth wave is a shear wave that propagates at a right angle to the other four. Test cases presented include a shock reflecting off a wall, a pure shear wave, supersonic flow over an airfoil, and viscous separated airfoil flow. Results using the new model give significantly sharper shock and shear contours than a grid-aligned solver. Navier-Stokes computations over an aifoil show reduced pressure distortions in the separated region as a result of the grid-independent upwinding.
    Keywords: AERODYNAMICS
    Type: AIAA PAPER 91-0239
    Format: text
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