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  • Chemistry  (3)
  • Physics
  • 1990-1994  (3)
  • 1975-1979
  • 1990  (3)
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  • 1990-1994  (3)
  • 1975-1979
Year
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 36 (1990), S. 994-1002 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Interpenetrating polymer networks (IPNs) of poly(ethylene oxide) (PEO) and a polyether substituted polysiloxane were synthesized containing variations of PEO content (35 and 65% dry network weight) and PEO systematically varied from low to high molecular weight (2,000, 8,000, and 20,000). Biocompatibility was assessed by measureing 111In platelet deposition in a baboon femoral ex vivo shunt. Mass transfer analysis revealed that platelet transport to PEO/polysiloxane surfaces was kinetically limited and correlated with both PEO content and molecular weight. Differences in material performance were noted particularly after the initial 30 min blood contact period. In mid and high PEO molecular weight networks (8,000 and 20,000), reduced platelet deposition was noted with increased PEO content. In materials of high PEO content (65%), mid and high PEO molecular weight samples had significantly lower levels of platelet adsorption than PDMS (60 min; p〈 0.05) or networks of low PEO molecular weight, coded 2K-65 (30 and 60 min; p 〈 0.05). The lowest level of platelet deposition was noted on 20K-65 networks, less than one platelet per 1,000 μm2.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 28 (1990), S. 149-176 
    ISSN: 0887-6266
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: As we have reported recently, the application of association models has provided a theoretical basis for the calculation of the free energy changes and phase diagrams of binary polymer blends in which hydrogen bonding plays a significant role. Here we report theoretical calculations of spinodal phase diagrams of a series of polyisophthalamide-polyether blends and compare the predictions with experimental observations of the miscibility of these polymer blend systems. The general agreement between theory and experiment is very encouraging and has important ramifications to discussions of polymer-induced crystallnity, the minimum number of hydrogen bonding sites necessary to ensure significant molecular mixing, and the effect of hydrogen bonding on the breadth of “miscibility windows.”
    Additional Material: 17 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 1299-1302 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A discussion is given of the unidirectional, but nonuniform stretch of long, wide strips of film. It is observed that each of the material functions, τ, β, γ, in a recently proposed unidimensional theory of neck formation and cold drawing for bars of small but not zero thickness is determined, in the case of a strip of film, by the strain-dependent shear modulus μ of the three-dimensional material of which the bar is composed. The dependence of the shear modulus μ on shear strain and of τ, β,and γ on axial stretch is evaluated for a model of an elastic material susceptible to cold drawing, and the calculated values of τ, β,and γ, are used to draw film profiles for various stages of neck formation.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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