Electronic Resource
Springer
Russian chemical bulletin
39 (1990), S. 1725-1728
ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract A method has been found for the synthesis of fluoride-containing α-hydrothionyl fluorides by heating polyfluoroalkenyl benzyl sulfides having fluoride atoms in the α-position relative to the sulfur atom with fluorosulfonic acid. The reactions of the acid fluorides obtained with secondary amines were studied. The reaction of the α-hydrotetrafluorothiopropionyl fluoride with NH(Me)2 leads to the amide of the corresponding acid, while the product of α-hydrohexafluorothioisobutyryl fluoride with diethylamine is the dimer of bis(trifluoromethyl)thioketene.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00961512
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