ALBERT

Description: ODP Legs 106 and 109 drilled zero-age crust at Site 648 on the axis of the Mid-Atlantic Ridge and recovered sparsely to moderately phyric but chemically homogeneous basalt. Plagioclase phenocrysts in Site 648 basalts exhibit a variety of zoning patterns and compositions including: (1) tabular (An84) cores mantled by more sodic zones (An80 and An75), (2) tabular (An80) cores mantled by narrow (An84 and An75) zones, (3) skeletal cores (An80-78) enclosing sodic (An75) patches, and (4) rounded cores (An75) surrounded by skeletal (An80-78) mantles. Backscattered electron images have been used to define zone morphologies in 28 crystals; major element compositions of the zones have been determined by electron microprobe; and Mg, K, Ti, Fe, and Sr concentrations have been determined by ion microprobe. Equilibrium partitioning of minor and trace elements between crystals and liquids occurred during stable growth of tabular cores and inner rims. Disequilibrium partitioning occurred during rapid growth of crystal rims, resulting in enrichment of incompatible trace and minor elements, and during growth of calcic zones with skeletal and acicular morphology, resulting in enrichment of Fe and Sr and depletion of Mg, K, and Ti. Crystal/liquid partition coefficients estimated from the composition of inner rims and glass are DMg = 0.03, DK = 0.15, DTi = 0.028, DFe = 0.05, and DSr = 1.82. Using these partition coefficients, we have calculated the composition of primitive liquid in equilibrium with phenocryst cores. The estimated liquid composition is similar to primitive basalt compositions from the Kane Fracture Zone except for a much higher Ca/(Ca + Na) ratio which resembles values for MAR plume basalts. The diversity in plagioclase morphologies and compositions is explained by mixing of melts at different stages of evolution and stored in separated but interconnected reservoirs, as previously suggested by Kuo and Kirkpatrick (1982, doi:10.1007/BF00376957).