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  • Chemical Engineering  (2)
  • Atomic, Molecular, and Optical Physics
  • Composites
  • Instable interface
  • SEM analysis
  • 1990-1994  (2)
  • 1991  (1)
  • 1990  (1)
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Keywords
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  • 1990-1994  (2)
Year
  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 314-320 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Dynamic-mechanical and dielectric characterization of the cold crystallization of PEEK has been performed in order to develop a non-destructive evaluation method of crystallinity in thermoplastic matrices. The Avrami approach is applied here to describe the Poly(ether ether ketone) (PEEK) crystallization kinetics after an appropriate reduction of dynamic-mechanical and dielectric parameters. Avrami exponents obtained from dielectric characterization are comparable with those obtained with DSC measurements reported in literature, while the exponents obtained from the dynamic-mechanical characterization are higher, reflecting also changes in the aspect ratio of the growing crystals. Variations in the glass transition temperature detected during cold crystallization are analyzed and analogies between PEEK and PET are discussed.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 12 (1991), S. 333-337 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The effect of water absorption on the stress transferability across E-glass fiber/nylon 6 interface has been studied using the embedded single fiber composite technique. The behavior of silane coated fiber and untreated fiber composites after periods of water immersion were compared. The silane coating provided both higher interfacial shear stress transferability and protection from permanent water damage in the interphase region. It was found that water absorption in the nylon matrix reduced the shear stress transferability through plasticization of the matrix, weakening of the interface, and the development of tensile swelling stresses at the phase boundaries. In untreated materials the shear stress transferability was limited by decoupling of the matrix from the broken fiber ends by either interface slippage or local plane strain fracture in the interphase region near the fiber end. In the silane treated materials the shear stress transferability was limited by constrained yielding of the polysiloxane/nylon interphase at the fiber end, thus indicating plasticization of the matrix was the primary factor. After 20 days of water immersion, there was permanent deterioration of stress transferability in the untreated samples, but very little permanent damage in the treated samples.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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