ISSN:
1573-1111
Keywords:
α-Tin(IV) hydrogen phosphate
;
intercalation
;
surface modification
;
monomers
;
trans-N,N′-diethyl-2-butene-1,4-diamine
;
4-vinylpyridine
;
tetraethylenepentamine
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Monomers which contain unsaturated linkages and amine groups have been intercalated to form either mono- or bi-layers. The monomertrans-N,N′-diethyl-2-butene-1,4-diamine (NNBD) has been intercalated into α-tin(IV) hydrogen phosphate. The guest molecule, NNBD, forms a monolayer (d 001 = 1.35 nm) in which the amine groups are paired to protons on opposite faces of the phosphate layers. The resultant compound has the formula Sn(C8H18N2)0.73(HPO4)2·H2O indicating that NNBD does not cover a large proportion of the available protons. 4-vinylpyridine slowly forms an intercalate in which the host molecule forms a bilayer (d 001 = 1.56 nn). However, with 4-vinylpyridine there is surface modification in preference to intercalation.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01076982
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