ISSN:
1573-1111
Schlagwort(e):
Benzene inclusion
;
cyclovoltammetry
;
electrochemistry
;
ester
;
host/guest chemistry
;
lactone
;
macrobicyclic compounds
;
macrocyclic molecules
;
triphenylamine units
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
Notizen:
Abstract The synthesis of a family of new host type molecules (1–4) bearing six lactone structural units is described. One of the lactones (1) forms crystals which contain benzene in a 1∶2 (host:guest) ratio. The complexation behaviour towards potential guest molecules and the electrochemical properties of the molecules are studied. Compared to an analogous open chained ester (18) the electrochemical potentials of the bicyclic lactones,1, 2 are higher due to the different steric environment.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF00663048
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