ISSN:
0570-0833
Keywords:
Pentazadienide ion
;
Coordination modes
;
N ligands
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The pentazadienide ion is a surprisingly versatile ligand. The planar, zigzag N5 chain can utilize its atoms N1, N3, and N5 to complex one, two, or three metal atoms in a monodentate or bidentate fashion. Of particular interest is the ligand's ability to promote short metal-metal contacts in complexes with d10 metal ions.
Additional Material:
10 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/anie.198808961
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