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  • Polymer and Materials Science  (5)
  • Organic Chemistry  (2)
  • 1985-1989  (7)
  • 1987  (7)
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Publisher
Years
  • 1985-1989  (7)
Year
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 70 (1987), S. 680-689 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Eight cyclic triamines with ring sizes between 9 and 13 were synthesized by the p-toluenesulfonate method. The open-chain triamines bis(2-aminoethyl)amine (dien) and bis(3-aminopropyl)amine (diprop) were used as starting materials. In some cases, the corresponding dimeric cyclic hexaamines have been isolated and characterized as major by-products. The complexation of Cu(I) by the triamines has been studied potentiometrically in CH3CN/H2O. All ligands L form ternary complexes [Cu(CH3CN)L]+. The corresponding association constants vary between 1011 and 107, decreasing with increasing ring size. In addition, complexes [Cu(CH3CN)yLH]2+, y = 1 or 2, are found as less important species with maximum concentrations of 7 to 50%.
    Additional Material: 2 Ill.
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  • 2
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Gloeosporone, the germination self-inhibitor from the fungus Colletotrichum gloeosporioides f.sp. jussiaea, is shown by spectroscopic data and X-ray analysis to have the constitution and relative configuration as shown in Formula 2 (either (1S,6R,12R)-1-hydroxy-6-pentyl-5,15-dioxabicyclo[10.2.1]pentadecan-4,13-dione or its enantiomer), rather than the previously assigned constitution 1.
    Additional Material: 3 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 188 (1987), S. 887-898 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Derivatives of silicic acid of the type Si6O5R18 and Si8O7R18 (R = Cl, OCH3, and OC2H5) as well as bicyclic Si8O9(OC2H5)14 were isolated and characterized by 29Si NMR. The spin-lattice-relaxation and the nuclear Overhauser enhancement factor of the esters were determined between 273 and 343 K. The temperature dependency of the dipolar contribution to the longitudinal relaxation time gave an energy of activation for the segmental motion of the siloxane skeleton of about 10 kJ/mol which is independent of the kind of building unit.
    Additional Material: 1 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 26 (1987), S. 1207-1225 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Prior to availability of the crystal structure of the complex, we evaluated models of the complex between porcine pancreatic elastase and a t-Boc-Val-derived benzoxazinone inhibitor. Models of the noncovalent and covalent complex were generated using computer graphics and each model was subjected to energy minimization using molecular mechanics. After the crystal structure became available, we found that the model with the lowest energy was in good agreement with the crystal structure, except for the position of the His57 side chain. Permissible conformations of the inhibitor were based on information from x-ray crystal structures and an earlier conformational energy investigation of t-Boc-amino acids. We did not, however, limit ourselves to these conformations. The conformation of the inhibitor in the lowest energy model and crystal structure, was not similar to any of the minimum-energy conformations of t-Boc-amino acids. This suggests that limiting proposed binding modes only to the lowest energy conformations of a ligand (prior to binding) may sometimes unfairly bias the procedure.
    Additional Material: 5 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 59 (1987), S. 695-700 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Ethanol production with bacteria. Strains of Saccharomyces cerevisiae have mostly been used for the production of ethanol from sugar by yeasts. Recently it was shown that the bacterium Zymomonas mobilis has some advantages compared to yeast for the production of industrial alcohol. Compared to traditional yeast fermentation, ethanol yield is about 5% higher than with yeast, since less sugar is incorporated into cell material by this bacterium. Like yeast, Zymomonas mobilis has remarkably high ethanol tolerance which enables the bacterium to produce ethanol concentrations of more than 13 vol.-% from sugar solutions of appropriate concentration. Investigations of the spectrum of lipids present have shown that this bacterium contains large quantities of hopanoids which are presumably of significance for the stabilization of cell membranes in the presence of ethanol. Since the cost of the sugar greatly influences the profitability fraction formed in the production of glucose syrup from wheat flour was investigated. It was shown that after enzymatic saccharification of this waste starch the glucose was efficiently fermented to ethanol by Zymomonas mobilis. It is planned to broaden the substrate spectrum of Zymomonas mobilis by gene cloning techniques so that in future pentoses, e. g. xylose or arabinose, can also be fermented to ethanol by this organism.
    Additional Material: 11 Ill.
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  • 6
    ISSN: 0009-286X
    Keywords: Kritische Wärmestromdichte ; Rohranordnung ; Sieden ; Verdampfen ; Wärmeübergang ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Basel : Wiley-Blackwell
    Die Makromolekulare Chemie, Rapid Communications 8 (1987), S. 151-157 
    ISSN: 0173-2803
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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