ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions 1. Under chemical ionization conditions, adamantane forms the ions M+. and [M-H]+, while 2,4-dehydroadamantane also gives protonated ([M + H]+) and alkylated ([M + Alk]+) ions. 2. Functional groups in the adamantane molecule undergo ready alkylation and protonation, and may be lost as the HX molecule. Protonation of the diazirine group results in the loss of a molecule of nitrogen. The diazirine group is protonated more readily than the hydroxyl group, but less readily than CN, CONH2, or COOCH3.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00958331
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