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  • Chemistry  (3)
  • 2020-2021
  • 2005-2009
  • 1985-1989  (3)
  • 1950-1954
  • 1987  (3)
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  • 2020-2021
  • 2005-2009
  • 1985-1989  (3)
  • 1950-1954
Year
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1698-1706 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Particulate expansion and minimum bubbling parameters (n, u′t, umB, εmB) are measured for fine carbon powders (dp = 44 and 112 μm) fluidized with synthesis gas (H2/CO = 0.8) at pressures within the range 2,070 〈 P 〈 12,420 kPa in an industrial, pilot-scale fluidized bed. Deviations between minimum bubbling (umB and εmB) and minimum fluidization (umf and εmf) conditions increase with increasing pressure, P. The expansion index, n, decreases with increasing P and always exceeds values recommended by Richardson and Zaki for solid/liquid systems. Particulate bed expansion for the fine powders is well characterized by the equations of Foscolo et al. and Abrahamsen and Geldart. The theory of Foscolo and Gibilaro adequately estimates the onset of bubbling for both powders at all P, provided that experimentally determined values of n and u′t, are applied. For the dp = 112 μm powder, the theory of Foscolo and Gibilaro is applicable with calculated values of ut and experimental values of n.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Beiträge zur Chemie der Alkylverbindungen von Übergangsmetallen 51. Darstellung und Charakterisierung der Organomangan (III)- Verbindung Na[Mn(C5H5)4]Bei der Reaktion von Mn(acac)3 mit NaC5H5 in Tetrahydrofuran entsteht kristallines, rotviolettes, diamagnetisches Na[Mn(η1-C5H5)4-n(η5 -C5H5)n]. Eine nähere Charakterisierung erfolgte durch das 1H-NMR-, IR- und UV-VIS-Spektrum sowie durch Leitfähigkeitsmessngen.
    Notes: At reaction of Mn(acac)3 with NaC5H5 in tetrahydrofuran solution Na[Mn(η1-C5H5)4-n(η5 -C5H5)n] was obtained as a crystalline, red-violet, diamagnetic organomanganese(III) compound, which was characterized by n.m.r., i.r., and electronic spectra and by conductivity measurements.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 548 (1987), S. 175-179 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Contributions to the Chemistry of Transition Metal Alkyl Compounds. 50. A non-common Organolanthanum CompoundLanthanum reacts with dibenzyl mercury in tetrahydrofuran as a solvent with splitting of solvent molecules and with formation of ethylene and a benzyl hydrido vinyloxide lanthanum complex of the composition C6H5CH2La(H)OCH=CH2 · 2 THF. This complex, primary well soluble in tetrahydrofuran, is extremely sensitive against air and moisture and undergoes a fast coordination polymerisation with a strong decrease of the solubility.The compound was characterized by elementary analysis, the hydrolysis and deuterolysis reaction, and by the i.r. spectra.
    Notes: Lanthan reagiert mit Dibenzylquecksilber in Tetrahydrofuran als Reaktionsmedium unter Spaltung von Lösungsmittelmolekülen zu Ethylen und einem Benzylhydridovinyloxid-lanthan-Komplex der Zusammensetzung C6H5CH2La(H)OCH=CH2 · 2 THF. Dieser anfangs in Tetrahydrofuran gut lösliche Komplex ist extrem luft- und feuchtigkeitsempfindlich und unterliegt rasch einer Koordinationspolymerisation unter starker Abnahme der Löslichkeit.Die Charakterisierung erfolgte durch Elementaranalyse, Verfolgung der Hydrolyse und Deuterolyse sowie Auswertung des IR-Spektrums.
    Type of Medium: Electronic Resource
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