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  • American Institute of Physics (AIP)  (2)
  • 1985-1989  (2)
  • 1986  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Resistivity of AuIn2+δ thin films (1986)
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 60 (1986), S. 2041-2045 
    Details
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The resistivity and residual resistance ratio of 31-nm films of AuIn2+δ have been measured for a series of precision vacuum-deposited films covering the range of −0.04≤δ≤0.12. Both the resistivity and the resistance ratio exhibit a strongly peaked dependence on δ around δ=0. The results are analyzed in terms of the Mayadas–Shatzkes theory of scattering in thin films which includes the effects of both surface and grain boundary scattering. The dominant contribution to the resistivity is due to grain boundary scattering. The grain boundary scattering coefficient is unusually large compared to published results on single-phase metal films. These findings are interpreted in relation to the structure of the films and to the presence of second-phase material (AuIn or In) in the grain boundaries.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.337206
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  • 2
    Electronic Resource
    Electronic Resource
    A dipole-supported state in cyanomethyl anion, the conjugate base of acetonitrile. Rotational band assignments in the electron photodetachment spectrum of −CH2CN (1986)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 84 (1986), S. 5284-5289 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We report the 1 cm−1 resolution electron photodetachment spectra of cyanomethyl anion and its deuterated analog, trapped and detected in an ion cyclotron resonance spectrometer. Many sharp resonances were observed in the threshold region corresponding to rovibrational transitions from the ground electronic state to a dipole-supported state of the anion which subsequently undergo electron autodetachment. An assignment of the rotational transitions has been carried out, yielding rotational constants. Using spectral band intensities, we have estimated the electron binding energy of the dipole-supported state as 0.020 (±0.006) eV. The adiabatic electron affinities of the neutral radicals ⋅CH2CN and ⋅CD2CN are found to be 1.560±0.006 and 1.549±0.006 eV, respectively. Features of the dipole-supported state in this system have been compared to those in acetaldehyde enolate.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.449938
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