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  • Articles  (102)
  • Chemical Engineering  (83)
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  • Articles  (102)
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  • 2000-2004
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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 751-764 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper describes reactive flow in permeable media based on a numerical model that assumes local thermodynamic equilibrium. The model simulates single-phase, one-dimensional flow with greater generality than any model in the current literature. The mathematical foundation for the formulation is discussed in some detail. Results for hypothetical examples demonstrate that ion exchange and precipitation/dissolution of solids can interact to produce wave behavior not possible with either phenomenon alone. An important application involving both ion exchange and precipitation/dissolution is alkaline flooding. Model predictions for several laboratory alkaline floods indicate that the assumption of equilibrium is justified for these experiments. Simple calculations based on the equilibrium theory provide estimates of pH loss and hydroxide penetration distance.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The two-scale turbulence concept is recommended for modeling the turbulence in a baffled vessel equipped with a Rushton-type turbine impeller. A three-equation isotropic turbulence model is proposed that employs the balance equations for: the kinetic energy of the large scale vortices; the kinetic energy of the inertial subrange eddies; and the dissipation rate of the small-scale turbulence. The energy transfer rate from the large-scale vortices is prescribed algebraically. Flow patterns are modeled by solving the transport equations for vorticity, stream function, and tangential momentum. The Reynolds stresses are modeled by means of the effective viscosity, based on the three-equation model of turbulence. The calculated profiles of the mean velocity at the tank wall agree with experimental data obtained in the same system by means of a Pitot tube.
    Additional Material: 14 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1963-1970 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: One hundred sets of R-11 two-phase pressure drop and boiling heat transfer data are reported for cocurrent down-flow over an in-line tube bundle. The pressure drop data agree with predicitions using the Diehl correlation. A new heat transfer correlation is reported, accounting for the observed convective and nucleate mechanisms.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 26 (1986), S. 1399-1404 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new capillary rheometer incorporated in an instrumented transfer molding press has been developed. This rheometer is effective for determining the viscosity characteristics of thermoset molding compounds under both isothermal and typical molding conditions. In examples of the rheometer's utility, the power law indices of two commercial epoxy molding compounds have been determined to be approximately 0.7. Additionally it has been shown that preconditioning typical epoxy compounds at 47 percent relative humidity causes a viscosity decrease of about 40 percent owing to plasticization of the epoxy resin.
    Additional Material: 11 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 26 (1986), S. 600-604 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Recovery experiments above Tg have been performed on polymeric liquid crystal (PLC) - polystyrene (PS) blend sheets obtained from extrusion and subsequent hot drawing. The data reported show that a significant improvement of the dimensional stability of a drawn thermoplastic material can be obtained by adding a low percentage of non-compatible polymeric liquid crystals that are oriented during the hot drawing process. The fibrils formed act as a constraint for a certain amount of polymer surrounding them and consequently these highly oriented sheets, once exposed to high temperature, will mainly stress relax and do not creep. This effect disappears when the melting temperature of the oriented crystalline phase is reached. Compatible PLC-PS blends do not show any improvement on the dimensional stability compared to the unfilled matrix.
    Additional Material: 6 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Plant/Operations Progress 5 (1986), S. 49-51 
    ISSN: 0278-4513
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Newly developed equations offer convenience in computer-aided design of pressure-relief devices.
    Additional Material: 1 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1036-1038 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1347-1359 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The technique of distillation with intermediate heat pumps and optimal sidestream return - IHOSR distillation - is presented. IHOSR distillation allows heat to be moved between points in a distillation column with greater efficiency than several other methods of using heat pumps for distillation.
    Additional Material: 15 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1561-1566 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 444-454 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The electrolyte nonrandom two-liquid (NRTL) model proposed by Chen et al. (1982) is generalized to represent the excess Gibbs energy of aqueous multicomponent electrolyte systems. Using only binary parameters, the model correlates and predicts the deviation from ideality of aqueous multicomponent electrolyte systems over the entire range of temperature and concentration.
    Additional Material: 5 Ill.
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