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  • Chemical Engineering  (75)
  • 2020-2024
  • 1995-1999
  • 1985-1989  (75)
  • 1955-1959
  • 1986  (75)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1971-1979 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Bimolecular QRRK (Quantum Rice-Ramsperger-Kassel) analysis is a simple method for calculating rate constants of addition and recombination reactions, based on unimolecular quantum-RRK theory. Input parameters are readily derived, and rate constants and reaction branching can be predicted with remarkable accuracy. Such predictive power makes the method especially useful in developing mechanisms of elementary reactions. Furthermore, from the bimolecular QRRK equations, limiting forms of the rate constants in the limits of low and high pressure are developed. Addition/stabilization is pressure-dependent at low pressure but pressure-independent at high pressure, as is conventionally understood for simple decomposition, its reverse. In distinct contrast, addition with chemically activated decomposition has the opposite behavior: pressure independence at low pressure and pressure dependence [as (pressure)-1] at high pressure. The method is tested against data and illustrated by calculations for O + CO → CO2; for H + O2 → HO2 or O + OH; for H + C2H4 → C2H5 or C2H3 + H2; and for H + C2H3 → C2H4 or H2 + C2H2.
    Additional Material: 9 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 163-166 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 657-666 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The extent to which dispersed-phase viscosity influences equilibrium mean drop size and drop size distribution at constant interfacial tension is determined for dilute suspensions by dispersing silicone oils of various viscosity grades in water. A mechanistic model for mean drop size is developed which predicts the moderate-viscosity data and whose parameters correlate the high-viscosity results. Trends in the mean size data coincide with those for the drop size distribution, which broadens considerably as viscosity increases and suggests a dependency on breakage mechanism.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 7 (1986), S. 91-95 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Multilayer printed circuits are a prime example of complex polymer composites. One of the critical steps in manufacturing of the circuit boards is the lamination process, which is frequently simulated by the aborted flows test (AFT). In order to obtain a composite free of voids and good interlaminar adhesion, it is imperative for the resin to flow into metal interfaces as well as intermix in the resin interfaces. On an empirical basis, the AFT is used as a process monitor for making prepreg, the glass fiber reinforced dielectric which supports the circuitry. Under a given set of conditions (temperature profile, pressure, layup), AFT measures advancement and reactivity of prepreg. By using a given batch of prepreg, the optimum laminating conditions can be identified, which are mainly a function of the temperature profile. Here, a calorimetric and rheological study of prepreg cure kinetics during lamination is presented. The flow process is being modeled by calculating the viscosity from combining a temperature dependent viscosity term with a kinetically controlled molecular weight term.
    Additional Material: 9 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1253-1262 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A universally valid formal expression for the composition dependence of solute and solvent fugacity coefficients in any dilute binary system far from criticality is derived in this paper. In the present context, dilution denotes the y1 → O limit, regardless of the mixture's molar density. The results are independent of the system under study and of the choice of equation of state. The solute fugacity coefficient is simply the product of a composition-independent term (the infinite dilution fugacity coefficient) and an exponential decay composition correction. These two parameters have important thermodynamic implications: their temperature and pressure derivatives are related to the solute's partial molar enthalpy and volume, respectively. When applied to activity coefficients, the same theoretical analysis yields universal relationships for the composition dependence of activity coefficients which can be used as consistency checks for empirical correlations. The relationship between infinite dilution activity and fugacity coefficients can be used to estimate relative solubilities of a given solute in different solvents. Excellent agreement is found when the theoretical expressions are tested with three different binary systems involving a nonvolatile solid solute and a supercritical fluid.
    Additional Material: 5 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1642-1654 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model for the variance σc2 of instantaneous plume concentrations, at a level corresponding to that of the Gaussian formulas for the mean field, is developed and tested against available data. Starting from the Eulerian species transport equation, theoretical and empirical information is used to estimate parameters and simplify the form of the transport equation for σc2 in a meandering frame of reference. Then, introduction of a localized production of fluctuations (LPF) scheme allows construction of analytical expressions for σc2 that provide a direct means for calculating the concentration variance inside the instantaneous boundaries of plumes resulting from continuous point emissions in turbulent flows with uniform mean velocity.
    Additional Material: 7 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1015-1024 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The multiinput/multioutput pole-placement self-tuning controller (MIMO PPSTC) previously developed by McDermott and Mellichamp is used to control a fixed-bed autothermal reactor with internal countercurrent heat exchange. The performance of the controller is demonstrated using step changes in the set points and in the primary disturbance variables. It is shown that the complete temperature profile can be maintained by controlling two temperatures in the catalyst bed: one just before the hot spot and the other at the exit of the bed. Simulated results using a 36th-order nonlinear reactor model operating at both an open-loop upper stable steady state and an open-loop unstable steady state are presented. Experimental results for a fixed-bed autothermal reactor operating at an upper stable state are presented.
    Additional Material: 12 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1138-1145 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A recently developed error-in-variables method of calculating regression parameters was applied to the modeling of gas-solid adsorption equilibria. The method accounts for error in all experimental variables in the regression calculations. Regression coefficients from pure component data calculated by the new method were used to predict multicomponent equilibria. The multicomponent predictions using pure component parameters calculated by the error-in-variables method were more accurae than predictions using parameters calculated by conventional least-squares regression.
    Additional Material: 11 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1205-1207 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 1574-1578 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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