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  • American Institute of Physics (AIP)  (9)
  • Oxford University Press  (5)
  • Blackwell Publishing Ltd  (4)
  • American Geophysical Union  (3)
  • American Association for the Advancement of Science (AAAS)
  • Amsterdam : Elsevier
  • Geological Society of London
  • 2020-2022
  • 1985-1989  (21)
  • 1960-1964
  • 1989  (8)
  • 1985  (13)
Collection
Publisher
Years
  • 2020-2022
  • 1985-1989  (21)
  • 1960-1964
Year
  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 90 (1989), S. 4619-4620 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The vibrational relaxation dynamics of CO chemisorbed on small Pt and Rh particles supported on SiO2 has been investigated by picosecond time-resolved infrared transient bleaching experiments. A vibrational T1 lifetime of ≈7 ps has been observed for several different samples, independent of polarization, pump intensity, and sample temperature from 100–400 K. A 1:3 isotopic dilution has no effect upon T1. This T1 lifetime is a factor of 10–50 times shorter than T1 reported for metal carbonyl cluster compounds in solution and on SiO2 supports. Two possible mechanisms are considered to account for the rapid T1 decay; redistribution of the energy throughout the broad CO vibrational band, and relaxation directly to electron–hole pairs in the metal particles.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 90 (1989), S. 3171-3180 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The A 3Π1←X 1Σ+ laser-induced fluorescence excitation spectrum of the NeIBr van der Waals complex is reported and analyzed to extract information regarding the structure and vibrational predissociation dynamics of the complex. While no definitive geometric information regarding NeIBr is obtained, our data indicate that a linear geometry is at least plausible. The vibrational predissociation lifetimes are a strong function of A state vibrational level and range from 2.6 to 23 ps. The variation in lifetime with vibrational level is consistent with the results of previous measurements on rare gas–halogen complexes, particularly NeBr2.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 90 (1989), S. 7037-7045 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Vibrational overtone photodissociation is used to examine the spectroscopy and vibrational predissociation lifetimes of HN3 in its ground electronic state. Direct overtone pumping of the N–H stretching levels 5νNH and 6νNH prepares molecules in selected states (v,J,K) near 15 100 and 17 700 cm−1 of vibrational energy; spin-forbidden NH(X 3 Σ−) dissociation fragments are detected by laser-induced fluorescence. Photodissociation spectra of beam-cooled HN3 display mixing of individual rotational levels of the nνNH vibrations with several background states, with derived coupling matrix elements in the range 0.01–0.1 cm−1. Vibrational predissociation lifetimes of mixed components of 5νNH are state specific, with variations of a factor of 2 for only 0.1 cm−1 energy differences. Average lifetimes for low J, K are 210 ns for 5νNH and 0.95 ns for 6νNH. The ratio of decay rates for the two overtone levels, k(6νNH)/k(5νNH)=220, is much greater than predicted by statistical theory, which gives a ratio of 4.
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Review of income and wealth 35 (1989), S. 0 
    ISSN: 1475-4991
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Economics
    Notes: This paper reports the detailed results of a comparison of the distribution and redistribution of income in seven countries using the Luxembourg Income Study (LIS) database. Use of LIS facilitates comparisons of inequality in respect to similarly-defined variables, permits methodological alternatives to be used, and allows the countries to be compared on aspects of income ranking and policy equity in ways not otherwise possible.The results indicate a pattern of inequality in which Sweden is the most equal, followed by Norway, the U.K. and Canada, while among the less equal countries Israel is generally more equal than Germany-or the USA., whose relative inequality depends on the measure chosen. Use of the LIS database also allows a more detailed explanation of these results, noting, for example, the role of cash benefits in increasing equality in Sweden and the U.K., and in aiding the bottom quintile in Germany; and the important part played by self-employment income in contributing to the high top quintile shares in Germany and Israel, and in rendering the Norwegian distribution less equal than that of its Scandinavian neighbour.The wealth of the database, however, means that methodological issues need to be treated both more explicitly and more carefully than is possible with more restrictive data. To interpret the data also requires a considerable degree of knowledge about the institutional features of tax and social provisions in each country, so that an income microdatabase could usefully be completed by one focused on the details of such provisions.
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  • 5
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 54 (1989), S. 2207-2209 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The effect of growth conditions on the stability of α-Sn films grown by molecular beam epitaxy on CdTe is studied. The growth conditions considered are substrate orientation, thickness, growth rate, and substrate temperature. The transition temperature from α-Sn to β-Sn, as determined by optical microscopy, is used as the measure of stability. It is shown that CdTe(110) is a somewhat better orientation than CdTe(100), and CdTe(111)B is totally unacceptable for the growth by molecular beam epitaxy of α-Sn films. The transition temperature from α-Sn to β-Sn shows a dependence on the total film thickness, with thinner films having a somewhat higher transition temperature than thicker. The quality of the films is the best when the growth rate is about 0.5 A(ring)/s and the growth temperature is about 75 °C. Since the transition from α-Sn to β-Sn starts at defects in the film, improving the quality of the film by lowering the growth rate and raising the growth temperature raises the transition temperature.
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  • 6
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: Time-resolved x-ray scattering studies of phase transition kinetics have been carried out using the wide-bandpass monochromator and fast linear position-sensitive detector system at the IBM/MIT beamline X-20C at the National Synchrotron Light Source (NSLS). We report here on the instrumentation that has been developed for these studies, and in particular on the methods used to measure, change, and control sample temperature with millisecond resolution.
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  • 7
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Teaching statistics 7 (1985), S. 0 
    ISSN: 1467-9639
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mathematics
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 57 (1985), S. 4226-4228 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A recent study on low-alloy, nonoriented, semiprocessed electrical steels indicated that at 60 Hz and 15 and 17 kG the anomalous loss per cycle Wa increased linearly with t2/ρ, i.e., Wa=Wao+kt2/ρ, where t is sheet thickness, ρ is resistivity, and Wao and k are empirical constants. The present study explores the above relationship over inductions B of 5 to 17 kG and frequencies f of 20 to 200 Hz. A separation of hysteresis loss Wh into synchronous and asynchronous components is also considered. Six laboratory heats with Si+Al〈1.1 wt. % were hot and cold rolled to 0.035, 0.07, and 0.11 cm. The sheets were annealed, critically strained, and decarburized. Longitudinal strips were tested with dc as well as ac current in a 25-cm Epstein frame. The above linear equation was generally valid. At each combination of B and f, the intercepts Wao were always positive, but the slopes k were negative at 5 and 10 kG and positive at 15 and 17 kG. Furthermore, a fifth of the Wa values were negative. The negative Wa and k were associated with lack of flux penetration. Wh, but not Wa, increased with increasing oxygen and decreasing grain size, and these effects resided in the B1.6 component of Wh.
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  • 9
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 82 (1985), S. 5286-5288 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The rotational level distribution of the NO fragments formed as a result of the predissociation of the vibrationally excited NO–C2H4 (ν7) van der Waals molecule was measured by laser excited fluorescence techniques. The distribution was found to be Boltzmann in character, described by the rotational temperature 75±15 K. An average kinetic energy release of ≈105 cm−1 per fragment, in an isotropic flux distribution, was determined from Doppler profiles of the NO fragments in selected rotational levels.
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  • 10
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 82 (1985), S. 2236-2239 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The rotational-, spin-, and lambda doublet-state distributions for nitric oxide (NO) formed in the CO2 laser multiphoton dissociation of methyl nitrite, CH3ONO, in a pulsed molecular beam are reported. Upon methyl nitrite photolysis by temporal square wave infrared laser pulses at 983 cm−1 of 50 ns duration and 800 MW/cm2 intensity, the low-lying rotational levels of the nitric oxide fragments formed in the 2Π1/2 (F1) and 2Π3/2 (F2) spin-orbit states exhibited Boltzmann-like population distributions, characterizable by the rotational temperatures TR (F1)=400±10 K and TR (F2)=530±100 K; the integrated populations for J〈30.5 of the two spin components were in the ratio F1/F2=2.7 : 1. For those highly rotationally excited levels with J(approximately-greater-than)24.5 there is no measurable spin preference, the level population depending solely on total internal energy Eint. There is no apparent preference for formation of either lambda doublet component and there is no observable fragment alignment, the nascent NO species exhibiting an isotropic distribution of angular momentum vectors.
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