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  • LUNAR AND PLANETARY EXPLORATION  (4)
  • ASTROPHYSICS  (2)
  • Engineering General  (2)
  • 2D NMR Steroids
  • 1995-1999
  • 1985-1989  (9)
  • 1945-1949
  • 1988  (5)
  • 1985  (4)
Collection
Publisher
Years
  • 1995-1999
  • 1985-1989  (9)
  • 1945-1949
Year
  • 1
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 21 (1985), S. 163-168 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A fully discrete stability and accuracy analysis of some algorithms for the one-dimensional heat equation is presented. Results illustrate that 2-pass explicit schemes which simultaneously employ lumped and coupled capacity matrices are capable of improved performance over the standard 1-pass explicit scheme.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 26 (1988), S. 214-223 
    ISSN: 0749-1581
    Keywords: RELAY 2D NMR ; 1H NMR ; 2D NMR Steroids ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Relayed coherence transfer (RELAY) two-dimensional NMR spectroscopy was demonstrated to be an effective technique for overcoming the problem of overlapping multiplets in the analysis of the 1H NMR spectra of steroids. Cross-sections through appropriate proton resonances resulted in resolved spectra of the spin systems for each of the saturated rings of the estrogenic hormones 17β- and 17α-estradiol. During RELAY experiments with a fixed delay time of 0.042 s it was possible to observe RELAY cross-peaks between H-11α and 18-CH3 which resulted from magnetization transfer via long-range coupling between 18-CH3 and H-12α. The difference in stereochemistry at C-17 of these estradiol epimers allowed an examination of the effect of substituent configuration on the RELAY cross-peak intensity in order to determine the ability of the RELAY method to provide qualitative structural information.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0748-8025
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: If bending moments converge at a sufficiently fast rate, it is proved that transverse shear stress resultants calculated from the moment equilibrium equation also converge. The result holds independent of the plate theory or type of element employed.
    Type of Medium: Electronic Resource
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  • 4
    Publication Date: 2019-06-28
    Description: A tool for exploring the evolution of X-ray emission from young SNRs is presented which employs a novel approach to the problem of time-dependent ionization in a shock-heated plasma. The solution of this problem is coupled to a spherically symmetric hydrodynamic calculation for the evolution of a point explosion in a uniform medium. The method is applied to Kepler's SNR, and two narrowly constrained classes of models which can simultaneously fit the spectral and morphological features of the object are found. One of these is a Sedov model in which the emission arises from shocked ambient gas, and the other is a reverse-shock model in which the SN ejecta is the dominant source of radiation. The emission from one specific model in each class is compared with the radial surface brightness profile, the 0.2-4.5 keV broadband spectrum, and the 1-3 keV moderate-resolution spectrum of the remnant. Reasonable fits are obtained in both cases.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 291; 544-560
    Format: text
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  • 5
    Publication Date: 2019-06-28
    Description: Thirty-six aluminous mare basalt fragments from breccia 14321 and other Apollo 14 basalts are statistically divided into two broad groups, comprising five subgroups, using La, Sm, and Yb data. Major element compositions, petrographic characteristics, and mineral compositions are similar for the five groups. However, there is an eight-fold increase in REE abundances from Group 5 to Group 1, with Group 1 having a REE pattern similar to KREEP. Groups 1 to 3 may be related by partial melting of a source similar to that proposed by Unruh et al. (1984) for feldspathic basalt 12038. However, Groups 4 and 5 cannot be as closely matched by larger degrees of partial melting of this source. Groups 1 to 4 could also be produced by assimilation of a KREEP component by a magma similar in composition to Group 5. Such a magma can be produced by partial melting of an olivine-orthopyroxene source that crystallized from a magma with chondritic relative REE abundances.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Journal of Geophysical Research, Supplement (ISSN 0148-0227); 90; C365-C37
    Format: text
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  • 6
    Publication Date: 2019-07-12
    Description: Electron microprobe and INAA were used to analyze forty spherules of Apollo 15 yellow-brown glass for major and trace elements. The glass is one of twenty-five high-Mg primary magmas emplaced on the lunar surface in pyroclastic eruptions. The abundances show that the magma was produced by partial melting of differentiated cumulates in the lunar mantle. Models to explain the possible source-regions of several Apollo 15 and Apollo 12 low-Ti mare magmas are presented.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Geochimica et Cosmochimica Acta (ISSN 0016-7037); 52; 2379-239
    Format: text
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  • 7
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    In:  Other Sources
    Publication Date: 2019-07-12
    Description: Zr/Hf ratios and other elemental data in 68 samples of various mare basalts, KREEP units, and lunar glasses have been determined using instrumental neutron activation analysis coupled with coincidence-anticoincidence counting for greater precision. The data are presented in order to quantify further the amount of Zr/Hf fractionation that has occurred during primordial crystallization and cumulate remelting or by any other process. Models of Zr-Hf evolution are developed to place additional constraints on the bulk lunar composition and on the effects of minor phases that may be responsible for the observed fractionations. The Hf-Ta fractionation in lunar compositions is also reviewed in order to characterize normal Hf(4+) versus Ta(4+) behavior and to delineate possible effects due to the oxidation of Ta(4+) to Ta(5+) during late-stage ilmenite crystallization.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Journal of Geophysical Research, Supplement (ISSN 0148-0227); 90; D31-D45
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  • 8
    Publication Date: 2019-07-12
    Description: Using the subdivision of Apollo 16 regolith breccias into ancient (about 4 Gyr) and younger samples (McKay et al., 1986), with the present-day soils as a third sample, a petrologic and chemical determination of regolith evolution and exotic component addition at the A-16 site was performed. The modal petrologies and mineral and chemical compositions of the regolith breccias in the region are presented. It is shown that the early regolith was composed of fragments of plutonic rocks, impact melt rocks, and minerals and impact glasses. It is found that KREEP lithologies and impact melts formed early in lunar history. The mare components, mainly orange high-TiO2 glass and green low-TiO2 glass, were added to the site after formation of the ancient breccias and prior to the formation of young breccias. The major change in the regolith since the formation of the young breccias is an increase in maturity represented by the formation of fused soil particles with prolonged exposure to micrometeorite impacts.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Earth and Planetary Science Letters (ISSN 0012-821X); 89; 2 Ju
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  • 9
    Publication Date: 2019-07-12
    Description: The medium energy X-ray detectors onboard the EXOSAT Observatory have been used to determine the gas temperature at several positions in the Coma Cluster of galaxies. Evidence is found at greater than 95 percent confidence for a higher temperature in the center of the cluster than in a position approximately 45 arcmin off-center. No difference in iron abundance is observed between the center and off-center regions and the equilibrium model for the distribution of elements in the Coma Cluster of Abramopoulos, Chanan, and Ku can be rejected with greater than 99.5 percent confidence, in favor of a model with more uniform composition. A phenomenological model is presented of the Coma Cluster, which is consistent with the data presented here, as well as the imaging data from the Einstein Observatory and the Tenma X-ray spectrum. The model has a central isothermal region of temperature about 9 keV extending to about 25 arcmin (about 1 Mpc). Beyond this radius the temperature falls as a polytrope with index about 1.6.
    Keywords: ASTROPHYSICS
    Type: Astrophysical Journal, Part 1 (ISSN 0004-637X); 329; 82-96
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