ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

X
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • Articles  (316)
  • Polymer and Materials Science  (220)
  • Analytical Chemistry and Spectroscopy  (96)
  • ASTROPHYSICS
  • INSTRUMENTATION AND PHOTOGRAPHY
  • 1980-1984  (316)
  • 1984  (316)
  • 1
    Electronic Resource
    Electronic Resource
    Synthesis of fibre-forming copolymers of acrylonitrile with acrylates in systems based on lithium alkoxides (1984)
    Weinheim : Wiley-Blackwell
    Acta Polymerica 35 (1984), S. 65-67 
    Details
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Copolymerisation von Acrylnitril und Acrylaten wurde in Dimethylformamid bei hohem Acrylnitril/Acrylat-Verhältnis im Temperaturbereich von -50 bis +10°C durch Lithiumalkoxide initiiert. Die Bedingungen zur direkten Präparation von Spinnlösungen der Copolymere wurden erarbeitet. Das Lösungsspinnen dieser Copolymere durch Orientierungsfällung ergab Fasern mit hohen Festigkeitswerten.
    Notes: The copolymerization of acrylonitrile with acrylates has been initiated by lithium alkoxides in dimethylformamide at a high acrylonitrile/acrylate ratio over the temperature range from -50 to 10°C. The conditions for a direct preparation of spinning solutions of the copolymers were determined. The solution-spinning of these copolymers by orientational precipitation yielded fibres exhibiting high strength properties.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/actp.1984.010350115
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 2
    Electronic Resource
    Electronic Resource
    Resonance Raman spectra of mononucleotides obtained with 266 and 213 nm ultraviolet radiation (1984)
    New York : Wiley-Blackwell
    Biopolymers 23 (1984), S. 2067-2081 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Resonance Raman spectra of the nucleoside 5′-monophosphates UMP, CMP, AMP, and GMP have been obtained with 266- and 213-nm radiation, the fourth and fifth harmonics of a Nd:YAG laser. The 266-nm radiation is resonant with the states giving rise to the first absorption band of the bases. The resulting spectra are in agreement with those reported previously using similar wavelength excitation but are generally of better quality. The 213-nm radiation is resonant with those states giving rise to the second strong absorption band of the bases. The spectra obtained with this wavelength show several new features relative to the 266-nm spectra, including strong enhancement of modes of the pyrimidines with a character similar to the e2g ν8 mode of benzene, relative enhancement of ring modes at 1580 and 729 cm-1 in AMP, and strong enhancement of the 1670-cm-1 C = O mode of GMP. These enhancements are discussed in terms of previously reported preresonance behavior and predicted intensities based on CNDO bond-order changes and normal-mode calculations. The results of a preliminary study of the effect of the interaction of GMP with cis-dichlorodiammineplatinum(II) on the 213-nm resonance Raman spectrum is also discussed.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bip.360231017
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 3
    Electronic Resource
    Electronic Resource
    Polymers from renewable sources, 1. Diamines and diisocyanates containing difurylalkane moieties (1984)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 185 (1984), S. 697-707 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Furan-based diisocyanates and diamines were prepared unambiguously as potential monomers for polyurethane and polyamide production, starting from methyl furoate and furfurylamine, respectively. The syntheses were optimized and the product identity was confirmed by elemental analysis, IR and NMR spectroscopy, and also by preparation of derivatives which were similarly characterized.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1984.021850408
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 4
    Electronic Resource
    Electronic Resource
    Polymers from renewable sources, 2Part 1: cf.1. Kinetics and polyurethane formation from furan-based diisocynates (1984)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 185 (1984), S. 709-723 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Novel furan-based diisocyanates (2a - c) were reacted with 1-butanol and basic kinetic studies were made. The results were compared with those obtained from 4,4′-methylenediphenylene diisocyanate (1) under similar conditions. The kinetics of these model reactions were found to be complex even in the presence of added catalysts. The isocyanates 2 studied, were shown to behave as benzylic type compounds with reactivities intermediate between those of aryl and alkyl diisocyanates. Comparative studies were made on segmented copolyurethanes prepared from 1 and from a furfuryl diisocyanate 2a having structural similarity to 1. The diol components used in these studies were 1,4-butanediol and polytetrahydrofuran. The segmented co-polyurethanes prepared from the furfuryl diisocyanate can thus be derived from a single naturally occurring source material, namely furfuraldehyde. These polymers were shown by differential scanning calorimetry and dynamic mechanical analysis to possess properties comparable to analogous copolyurethanes derived from oil-based sources.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1984.021850409
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 5
    Electronic Resource
    Electronic Resource
    Deactivation of fused silica capillary columns with polymethylhydrosiloxanes (1984)
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 329-332 
    Details
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Fused silica capillary columns ; Deactivation ; Polymethylhydrosiloxanes ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jhrc.1240070608
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 6
    Electronic Resource
    Electronic Resource
    Polarizable biphenyl polysiloxane stationary phase for capillary column gas chromatography (1984)
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 13-18 
    Details
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Capillary columns ; Biphenyl polysiloxane ; Stationary phase ; Polarizable phase ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A crosslinkable biphenylmethylpolysiloxane stationary phase was synthesized for capillary column gas chromatography and compared with methyl, phenyl, and cyanopropyl polysiloxane stationary phases for the separation of isomeric polycyclic aromatic compounds. While the new phase gave similar separations of nonpolar isomers when compared to the nonpolar phases, separations of polar isomers were greatly improved because of the induced polarity of the biphenyl group of the stationary phase by the solute molecules. This polarizable stationary phase offers a unique selectivity which is not available in other stationary phases.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jhrc.1240070103
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 7
    Electronic Resource
    Electronic Resource
    Effects of viscous solvent on DNA polymer in a fiber (1984)
    New York : Wiley-Blackwell
    Biopolymers 23 (1984), S. 913-922 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The viscous forces acting on a DNA macromolecule in a fiber are calculated. The DNA polymer is modeled as an infinite rod of elliptical cross section with a grooved surface. The viscous solvent is hydrodynamic water. Appropriate boundary conditions for determining the viscous forces on the acoustic vibrational modes are discussed. The viscous forces acting on each mode are then calculated as functions of both frequency and amount of water in the fiber. The mass loading of the DNA due to water in the grooves is shown to reduce the longitudinal acoustic velocity, which agrees with recent experimental results. The longitudinal modes are determined to be underdamped and correspondingly sharp over a range of frequencies and humidities appropriate to experimental conditions. The torsional and transverse acoustic modes are still strongly overdamped.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bip.360230508
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 8
    Electronic Resource
    Electronic Resource
    Sequential hydration of dry proteins: A direct difference IR investigation of sequence homologs lysozyme and α-lactalbumin (1984)
    New York : Wiley-Blackwell
    Biopolymers 23 (1984), S. 1647-1666 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Direct difference ir spectra are presented as a function of hydration for lysozyme and α-lactalbumin, and detailed sequential hydration molecular events identified. Despite the strong sequence homology between the two proteins, and their expected conformational similarity, the hydration behaviour of the polar groups is different for the two proteins. Using a Hill-type analysis, we conclude that the acid groups ionize and hydrate rapidly and noncooperatively in both proteins, consistent with the known (lysozyme) and postulated (α-lactalbumin) surface chemistry. The polar group hydration shows a clear cooperativity, which is quantitatively different in the two proteins. Complementary work suggests this cooperativity relates to a hydration-induced “loosening up” of the lysozyme conformation at about 55 mol water/mol protein. α-Lactalbumin appears to “open up” more easily for hydration than does lysozyme, consistent with its lower stability against thermal and acid denaturation.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bip.360230904
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 9
    Electronic Resource
    Electronic Resource
    Microphase state of oligobutadienediol-based polyurethaneureasCorrected proofs received March 26, 1984 (1984)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 29 (1984), S. 1919-1927 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Structural studies of oligobutadienediol-based polyurethanes with various degrees of crosslinking were carried out. From absolute small-angle X-ray scattering, the degree of segregation of components was determined. It was concluded that a complete microphase separation of the different components is realized in all samples irrespective of the degree of crosslinking, and these polymers are two-phase systems. While stretching, the fibrillar structure is formed.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1984.070290601
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 10
    Electronic Resource
    Electronic Resource
    Homo- and copolymerization with a highly active Ziegler-Natta catalyst (1984)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 29 (1984), S. 279-289 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The copolymerization of ethylene and 1-butene with a highly active Ziegler-Natta catalyst has been investigated at different temperatures. The r parameters and the propagation rate constants have been determined. From the temperature dependence of the rate constants, entropy and enthalpy values have been calculated. These data show the enthalpy values to be small in comparison to entropy, which means that these processes are predominantly controlled by entropic factors.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1984.070290126
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...