ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Dicarbonyl(η5-cyclopentadienyl)molybdenum Complexes with 2-Iminocarboxylate as Chelate Ligand)A series of chiral 2-iminocarboxylato complexes (η5-C5H5)(CO)2MoN(R2)=C(R1)COO (1) (R1 = H, Me, Et, i-Pr; R2 = H, Me, Ph, OH, NH2, NHPh, (S)-CHMePh, CH2CO2Et) has been prepared from (η5-C5H5)(CO)3MoCl, the sodium salt of 2-oxocarboxylic acid and R2NH2 and spectroscopically characterized (IR, 1H NMR). Diastereomers of 1 have been obtained with (S)-1-phenylethylamine as amine component.
Notes:
Eine Reihe von chiralen 2-Iminocarboxylato-Komplexen (η5-C5H5)(CO)2MoN(R2)=C(R1)COO (1) (R1 = H, Me, Et, i-Pr; R2 = H, Me, Ph, OH, NH2, NHPh, (S)-CHMePh, CH2CO2Et) wurde aus (η5-C5H5)(CO)3MoCl, dem Natriumsalz der 2-Oxocarbonsäure und R2NH2 dargestellt und IR- und 1H-NMR-spektroskopisch charakterisiert. Mit (S)-1-Phenylethylamin als Aminkomponente wurden Diastereomere von 1 erhalten.
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19841170233
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