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  • Wiley-Blackwell  (52)
  • 2000-2004
  • 1995-1999  (34)
  • 1980-1984  (18)
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  • 1930-1934
  • 1995  (34)
  • 1984  (18)
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  • 2000-2004
  • 1995-1999  (34)
  • 1980-1984  (18)
  • 1970-1974
  • 1930-1934
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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 516 (1984), S. 30-34 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Crystal Structure of BaHg(CN)4 · 4 PyridineThe structure of the tetragonal BaHg(CN)4 · 4 Pyridine (space group I4, a = 1119.4(7), c = 1 057.9(7) pm, Z = 2, dc = 1.87 g · cm-3) contains tetrahedral Hg(CN)4 and bisdisphenoide Ba(NC)4(py)4 groups, which are linked together by Hg—CN—Ba bridges. The BaHg(CN)4 framework consists of a 3-dimensional network of all round edge-sharing tetrahedrons. The analogous strontium compound is isotype with a = 1 108.2(9) and c = 1 035.3(14) pm.
    Notes: In der Struktur des tetragonalen BaHg(CN)4 · 4 Pyridin (Raumgruppe I4, a = 1119,4(7), c = 1 057,9(9) pm, Z = 2, dc = 1,87 g · cm-3) sind tetraedrische Hg(CN)4- und bisdisphenoide Ba(NC)4(py)4-Gruppen über Hg—CN—Ba-Brücken zu einem Raumnetz verknüpft. Dem BaHg(CN)4-Gerüst liegt ein Aufbau aus allseitig eckenverknüpften Tetraedern zugrunde. Die analoge Strontium-Verbindung ist isotyp mit a = 1 108,2(9) und c = 1 035,3(14) pm.
    Additional Material: 2 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 37 (1995), S. 123-142 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Secondary structure investigations, affinities, and activities of neuropeptide Y analogues with respect to the Y1 and the Y2 receptor are reviewed. The results are discussed with respect to the different prerequisites for affinities to both receptor subtypes. The results from a systematic scanning of the hormone using L-alanine and from a large variety of discontinuous and cyclic analogs suggest that two different conformations of neuropeptide Y are adopted at the Y1 and Y2 receptors. Whereas a C-terminal turn structure is suggested for Y1 receptor affinity, an α-helical conformation of the C-terminus is afforded for good binding to the Y2 receptor. © 1994 John Wiley & Sons, Inc.
    Additional Material: 9 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 26 (1984), S. 467-481 
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The two lowest bound excited states of the Be- ion, 1s2 2s2p2 4P and 1s2 2p3 4S0, and their respective thresholds, Be 1s2 2s2p 3P0 and Be 1s2 2p2 3P, and the thresholds of these, Be+ 1s2 2s and Be+ 1s2 2p, have been examined using many-body methods. Here, we present the electron affinities (EAs) or ionization potentials, fine and hyperfine structure, and the electric dipole transition probabilities associated with these states and compare them with existing theory and experiment when available. Based on our new EA, a suggestion is made as to why no negative ion transition has yet been seen in the laboratory.
    Additional Material: 5 Tab.
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 117 (1984), S. 1003-1012 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Dichloropalladium(II) Complexes with α-Amino Acids, α-Amino Acid Esters, Dipeptides, and Dipeptide EstersA series of trans-dichloropalladium(II) complexes Cl2PdL2 (L = α-amino acid, α-amino acid ester, dipeptide, dipeptide esters) and cis-Cl2Pd(histidine) has been prepared and spectroscopically characterized. The X-ray structure of trans-Cl2Pd(GlyOEt)2 (3b) has been determined.
    Notes: Eine Reihe von trans-Dichloropalladium(II)-Komplexen Cl2PdL2 mit (L = α-Aminosäure, α-Aminosäureester, Dipeptid, Dipeptidester) sowie cis-Cl2Pd(Histidin) wurde dargestellt und spektroskopisch charakterisiert. Die Röntgenstruktur von trans-Cl2Pd(GlyOEt)2 (3b) wurde bestimmt.
    Additional Material: 1 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 117 (1984), S. 1241-1245 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reactive Platinum Complexes with α-Amino Acid Derivatives and their 31P- and 15N Nuclear Magnetic Resonance SpectraThe α-amino acidate chelate complexes (n-Bu3P)(Cl)⊓PtNH2CH(R)COO (1a - c) (R = H, CH3, CHMe2) react with thionyl chloride, phosphorus pentachloride, or acetyl chloride by cleavage of the chelate ring to give complexes with α-amino acyl chloride or acetic glycine anhydride as ligands: (n-Bu3P)Cl2Pt(NH2CH2COCl) (2), (n-Bu3P)Cl4Pt(NH2CH(CHMe2)COCl) (6), (n-Bu3P)-Cl2Pt(NH2CH2CO(O)OCCH3) (4). Using 15N enriched amino acids, the IR, 15N and 31P NMR spectra indicate cis orientation of phosphane and amino groups in all these complexes.
    Additional Material: 3 Tab.
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 117 (1984), S. 3169-3174 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Organometallic Lewis Acids, XV1). Cyclodimerization of 2-Butyne and 2-Pentyne at Pentacarbonyl(tetrafluoroborato)rhenium to a Coordinated Methylenecyclobutene DerivativeThe reactions of pentacarbonyl(tetrafluoroborato)rhenium, (OC)5ReFBF3 (1a), with 2-butyne and 2-pentyne give the methylenecyclobutene complexes [(CO)5Re(C8H12)]+BF4- (2) and [(CO)5Re(C10H16)]+BF4- (3). From 2, 3 the methylenecyclobutene ligands can be liberated by halide ions.
    Additional Material: 1 Tab.
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  • 7
    ISSN: 0009-2940
    Keywords: Fullerene ; Hydrofulleride ; Manganese complex ; Rhenium complex ; Iron complexes ; Ruthenium complex ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Addition of Hydrofulleride [C60H]- to Coordinated, Unsaturated Hydrocarbons: Binding of Fullerene to Metal Complexes through Hydrocarbon BridgesHerrn Professor Herbert Walter Roesky zum 60. Geburtstag gewidmet.Hydrofulleride [C60H]- is added to the hydrocarbon ligands of the cationic complexes [(OC)5Re(η2-C2H4)]+, [(OC)3Mn-(η6-C6H6)]+, [(OC)3M(η5-C6H7)]+ (M = Fe, Ru), [(OC)3Fe(η5-C7H9)]+, and [(η5-C5H5)Fe(η6-C5H4CH2)]+.
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  • 8
    ISSN: 0009-2940
    Keywords: 1,7-Dimethylocta-2,6-diene-1,8-diyl ; Ruthenium complexes ; α-Amino carboxylates ; α-Amino acid esters ; Peptide esters ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Metal Complexes Containing Biologically Important Ligands, LXXXLXXIX. Mitteilung: Lit. .  -  (η3:η3-C10H16)Ru(IV) Complexes with α-Amino Carboxylates, α-Amino Acid Esters, and Peptide Esters as LigandsReactions of the chloro-bridged bis(allyl) complex [(η3:η3-C10H16)Ru(Cl)(μ-Cl)]2 with α-amino carboxylates and α-amino acid esters afford the complexes (η3:η3-C10H16)(Cl)RuNH2CHRCO2 (2) and (η3:η3-C10H16)(Cl)2-RuNH2CHRCO2R′ (3). Abstraction of chloride from 3 by Ag+ gives the N,O-chelates [(η3:η3-C10H16)(Cl)RuNH2CHRCO2R′]+BF4 (4). Cysteine methyl ester forms the N,S-chelate complex (η3:η3-C10H16)(Cl)RuNH2CH(CO2CH3)CH2S (5), and with histidine methyl ester a dinuclear complex 6 with N,N-histidine bridge is obtained. Compound 3d with L-PheOEt as ligand was characterized by X-ray diffraction.
    Additional Material: 3 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 128 (1995), S. 23-27 
    ISSN: 0009-2940
    Keywords: cyclo-Hexatellurium(2+) ; 1,4-Diiodo-cyclo-hexatellurium(2+) ; Hexachlorotungstate(V) ; Tetrachlorooxotungstate(V) ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: WOCl4 reacts at 200°C with tellurium in a sealed, evacuated ampoule with the formation of Te6(WOCl4)2. The structure consists of six-membered tellurium rings in a boat conformation with significant transannular interactions and of pyramidal WOCl4 units which are linked by linear asymmetric O...;W=O bridges to polymeric (WOCl4)n, chains. The observed paramagnetism is consistent with the ionic formulation Te2+6[(WOCl-4)2]n. In the reaction of WCl6, I2 and Te in a 2:1:6 ratio Te6I2(WCl6)2 is formed at 150°C. The crystal structure consists of Te6I2+2cations and of slightly distorted octahedral WCl-6 anions. The Te6I2+2 ions are isostructural with Se6I2+2 and consist of a six-membered ring of Te atoms in the chair conformation with two I atoms bound in the 1,4-positions.
    Additional Material: 6 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 117 (1984), S. 827-832 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Dicarbonyl(η5-cyclopentadienyl)molybdenum Complexes with 2-Iminocarboxylate as Chelate Ligand)A series of chiral 2-iminocarboxylato complexes (η5-C5H5)(CO)2MoN(R2)=C(R1)COO (1) (R1 = H, Me, Et, i-Pr; R2 = H, Me, Ph, OH, NH2, NHPh, (S)-CHMePh, CH2CO2Et) has been prepared from (η5-C5H5)(CO)3MoCl, the sodium salt of 2-oxocarboxylic acid and R2NH2 and spectroscopically characterized (IR, 1H NMR). Diastereomers of 1 have been obtained with (S)-1-phenylethylamine as amine component.
    Notes: Eine Reihe von chiralen 2-Iminocarboxylato-Komplexen (η5-C5H5)(CO)2MoN(R2)=C(R1)COO (1) (R1 = H, Me, Et, i-Pr; R2 = H, Me, Ph, OH, NH2, NHPh, (S)-CHMePh, CH2CO2Et) wurde aus (η5-C5H5)(CO)3MoCl, dem Natriumsalz der 2-Oxocarbonsäure und R2NH2 dargestellt und IR- und 1H-NMR-spektroskopisch charakterisiert. Mit (S)-1-Phenylethylamin als Aminkomponente wurden Diastereomere von 1 erhalten.
    Additional Material: 3 Tab.
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