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  • Chemical Engineering  (145)
  • Wiley-Blackwell  (145)
  • American Meteorological Society (AMS)
  • National Academy of Sciences
  • PANGAEA
  • 1990-1994  (70)
  • 1980-1984  (75)
  • 1993  (70)
  • 1984  (75)
Collection
Publisher
  • Wiley-Blackwell  (145)
  • American Meteorological Society (AMS)
  • National Academy of Sciences
  • PANGAEA
Years
  • 1990-1994  (70)
  • 1980-1984  (75)
Year
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 39 (1993), S. 867-875 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A continuous electrochemically modulated complexation (EMC) process was devised to extract and concentrate a class of heterocyclic nitrogen compounds. This design is composed of flow-through electrolysis cells for redox modulation and cycling of the complexing agent and hollow-fiber membrane modules for phase contacting. The extent of both extraction and concentration was found to depend mainly on the magnitude of the distribution coefficients for both steps. Experimental results and modeling of this continuous EMC process are reported, as well as potential applications for this process for other separations.
    Additional Material: 16 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 39 (1993), S. 1164-1177 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The direct oxidation of CH4 to H2 and CO in O2 and in air at high temperatures over alumina foam monoliths coated with high loadings of Pt and Rh has been simulated using a 19-elementary-step model of adsorption, desorption and surface reaction steps with reaction parameters from the literature or from fits to previous experiments. The surface reaction model for Pt is in good agreement with previously reported low-pressure(0.1 to 1 torr) reactor measurements of CH4 oxidation rates at temperatures from 600 to 1,500 K and of OH radical desorption during CH4 oxidation at 1,300 to 1,600 K over polycrystalline Pt foils. The model predictions for both catalysts are also consistent with product selectivities observed over monolithic catalysts in an atmospheric-pressure laboratory-scale reactor, and the differences between Pt and Rh can be explained by comparing individual reaction steps on these surfaces. Because of the good agreement between the model and both low-and atmospheric-pressure reactor simulations, a complete energy diagram for methane oxidation at low coverages is proposed. The model results show that under CH4rich conditions at high temperatures, H2 and CO are primary products of the direct oxidation of methane via a pyrolysis mechanism.
    Additional Material: 9 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 679-682 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 492-494 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 967-973 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A general equation is derived that predicts the evolution of pore volume distribution during isothermal gasification in the regime of kinetic control, starting from a given initial condition. The development takes into account pore enlargement as well as pore intersections. Equations are also derived for the special cases of (1) uniform pore size and (2) bimodal distribution. The results are used to interpret the experimental data of Tomkow et al. (1977) and Kawahata and Walker (1962).
    Additional Material: 7 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 56-62 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Rate studies are reported of the effect of rehydration-dehydration cycling on the vapor hydration behavior of solid K2CO3. Isothermal rate data were obtained at different temperatures and water vapor pressures for the reaction of narrowlysized anhydrous particles. Effects of different particle preparation histories on the rehydration rate were investigated and correlations of rate with particle pore structure explored. Rehydration rates of dehydrated K2CO3·3/2H2O were found to depend on the conditions of the prior dehydration. Rehydration is comparatively very slow at relative pressures below P/Peq ≃ 1.5; rates increase linearly with pressure above P/Peq ≃ 3. Hydration rates of K2CO3 particles obtained as anhydrous are substantially slower than those of identically-sized crystals produced by prior dehydration of K2CO3·3/2H2O; after one rehydration-dehydration cycle, rehydration rates are increased by as much as two orders of magnitude and this distinction between sources virtually disappears. Diffusional resistances based on calculated water vapor diffusivities are qualitatively consistent with the observed effects of cycling but do not by themselves account fully for the observations.
    Additional Material: 10 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 557-563 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A mechanism is proposed for the dehydration-rehydration process in solid inorganic salts, and model rate equations are derived and applied to the observed behavior of potassium carbonate. Quantitative expressions for the effect of pressure on the reaction rates are derived using basic principles from nucleation and heterogeneous phase transformation theory. Model equation predictions agree with experimental dehydration and rehydration rate data at all but extreme pressures. The basic rate equation is also used to interpret the data of Eckhardt and Flanagan (1964) for the effect of pressure on the dehydration of manganous formate dihydrate. The mechanism on which the model equations are based is also consistent with the observed effects of cycling and of high temperature pretreatment on the K2CO3 rehydration rate.
    Additional Material: 8 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 849-853 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 829-831 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 33 (1993), S. 716-720 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A numerical model of the reaction injection molding process was developed to test front shape and flow approximations employed in previous models. The model was two-dimensional and simulated the flow, reaction, and heat transfer in the typically long axial dimension and the typically small thickness dimension of a mold. The filling front shape and the velocity profiles in the filling fluid were determined by numerical solution of the momentum equation with the appropriate stress boundary conditions using the method of Patankar (1980). The predicted temperature and conversion results agreed with calculations assuming that the front was flat perpendicular to the flow and that a parabolic velocity profile existed behind the fountain flow region at the front. Thus, simple assumptions about front shape and velocity in the thin dimension of a reaction injection mold can be employed without significant loss of accuracy in modeling reaction injection molding.
    Additional Material: 5 Ill.
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