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Methyl thiirane: Kinetic gas-phase titration of sulfur atoms in SX OY systems (1983)

Martinez, Richard I. ; Herron, John T.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 15 (1983), S. 1127-1132

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The reaction SO + SO →l S + SO2(2) was studied in the gas phase by using methyl thiirane as a titrant for sulfur atoms. By monitoring the C3H6 produced in the reaction \documentclass{article}\pagestyle{empty}\begin{document}$ {\rm S} + {\rm CH}_3\hbox{---} \overline {{\rm CH\hbox{---}CH}_2\hbox{---} {\rm S}} \to {\rm S}_2 + {\rm C}_3 {\rm H}_6 (7) $\end{document}, we determined that k2 ≃ 3.5 × 10-15 cm3/s at 298 K.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550151102

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