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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 55 (1983), S. 931-939 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Motion of fine grained particles, suspended in turbulent flow. This article considers the motion of particles, suspended in turbulent flow. If the particles are sufficiently small to respond to turbulence, their motion includes stochastic components. Concerning processes like air classification or separation of fine powders the stochastic contribution - characterized by the conception of a particle diffusivity - the particle motion exhibits a detrimental influence. Sharpness of cut and separation efficiency are reduced. The paper aims to present the state of the art in particle diffusion. First, theoretical investigations are reported, attention being focused on the equation of motion of the particle which is the link between the motion of the fluid and the motion of the particle. Then, experimental results are reviewed. The following tendencies can be seen: Particles which response to turbulence of fluid flow show increasing diffusivity with increasing inertia. Field forces like gravity or electrical field forces exhibit a damping effect on diffusivity.
    Additional Material: 1 Tab.
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 185 (1984), S. 991-1001 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Thermal degradation of polystyrene (PS) was carried out in the absence of oxygen between 292 and 336°C. The formed volatile products were analysed qualitatively and quantitatively by means of gas charomatography. It was found that the composition of the volatile fraction is a function of conversion and independent of temperature for most of the products. A radical chain mechanism is proposed to explain these experimental results.
    Additional Material: 3 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 185 (1984), S. 2205-2212 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The influence of branching on the radius of gyration and the hydrodynamic radius of dextran macromolecules was studied by elastic and quasielastic light scattering (ELS and QELS). The hydrodynamic radius is more sensitive to low levels of branching than the radius of gyration. At higher branching levels a saturation of the hydrodynamic radius rh is observed, while the radius of gyration rG still changes distinctly. The ratio rG/rh proves to be a measure of the flexibility of the macromolecules; the latter is increasing with molecular weight for short linear chains and is decreasing with increasing degree of branching. Measurements were carried out in water (thermodynamically good solvent) and in ethylene glycol (under theta conditions) on four series of dextran fractions having rather narrow molecular weight distributions.
    Additional Material: 3 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 34 (1983), S. 583-592 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Investigations on the corrosion and corrosion protection of seawater cooled condensor tubes of copper-base alloys - Experiments with rotating samplesExperiments have been done on rotating disc and cylinder electrodes of CuZn20Al2, CuNi10Fe and CuNi30Fe in 3 w/o sodium chloride solution and in artificial sea water at 25 and 40 ° C.Erosion corrosion of sea water cooled tube condensors should be simulated and studied.The corrosion mechanism of copper base alloys in clean and polluted sea water was intensely studied with particular consideration to the influence of ammonia, sulfides and chlorine. The effectiveness of iron sulfate dosing was tested.With the rotating samples under test no erosion corrosion could be detected on free corroding specimens.
    Notes: An rotierenden Scheiben und Zylinderproben aus CuZn20Al2, CuNi10Fe und CuNi30Fe wurden Korrosionsversuche in 3%iger Natriumchloridlösung und in synthetischem Meerwasser bei 25 und 40 ° C durchgeführt. Dabei sollten auch die Vorgänge bei der Erosionskorrosion von meerwassergekühlten Rohrkondensatoren simuliert und untersucht werden. Es wurden umfangreiche Messungen zum Korrosionsmechanismus der Kupferbasislegierungen in sauberem und verunreinigtem Meerwasser durchgeführt, wobei der Einfluss von Ammoniak, Sulfiden und Chlor sowie die Wirksamkeit der Eisensulfatdosierung untersucht wurden. An den verwendeten rotierenden Proben konnte bei freier Korrosion keine Erosion erzeugt werden.
    Additional Material: 13 Ill.
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  • 5
    ISSN: 0009-286X
    Keywords: Chemische Kinetik ; Kohlenwasserstoff-Pyrolyse ; Modellierung komplexer Reaktionen ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 56 (1984), S. 146-147 
    ISSN: 0009-286X
    Keywords: Flammen ; Verbrennung ; Deflagration ; Druckaufbau ; Zündgeometrie ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 7
    ISSN: 0009-286X
    Keywords: Turbulente Mehrphasenströmung ; KorrelationsMeßverfahren ; Schwankungsgeschwindigkeiten der Partikeln ; Ansprechverhalten von Partikeln auf Turbulenz ; Spektren ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 15 (1983), S. 475-502 
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The kinetics of the pyrolysis of n-hexane was studied in a conventional static reactor over a temperature range of 650-840 K. The overall reaction is essentially first order with the kinetic parameters A = 1013.92 s-1 and EA = 260.3 kJ/mol. The distributions of the main products were analyzed by gas chromatography. A reaction model involving 240 elementary reactions was developed to describe the experimental rate data. The agreement of the model with experimental data was surprisingly good over a wide range of temperatures and pressures and up to medium extents of conversion. Methods for sensitivity studies based upon the quasi-stationary-state assumption (QSSA) were developed, and for a number of more detailed effects, such as self-inhibition, explanations could be given. It was also shown that the hexyl isomerization reactions influence strongly the product distribution. The outstanding capability of kinetic modeling with computer simulations in handling complex kinetic systems is demonstrated.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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