ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary The following mono-, di- and tetra-nuclear rhodium carbonyl derivatives with silanolato and disilanolato ligands were prepared: Rh(CO)(PR′3)2(OSiR3), [Rh(CO)2(OSiR3)]2, Rh2(CO)3 (PBu3)(OSiR3)2 and Rh4(CO)8(OSiPh2)2 (R = Me or Ph; R′ = n-Bu or Ph). The complexes may serve as models for the bonding of transition metals on silica surfaces.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00618010
Permalink