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  • Articles  (6)
  • Analytical Chemistry and Spectroscopy  (3)
  • Polymer and Materials Science  (2)
  • Atomic, Molecular and Optical Physics
  • Gonadotrops
  • 1980-1984  (6)
  • 1982  (6)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 21 (1982), S. 711-716 
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A method within the PCILO framework for the study of periodic molecular systems involving impurities is described regarding a one-dimensional chain. The calculation of the whole system is reduced to the calculation of subsystem pairs only. By use of the first-neighbor approximation only one or two subsystem pairs must be considered for subsystems with identical or differing surroundings, respectively. The procedure described yields the ground state energies and charge distributions of the subsystems.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 5 (1982), S. 19-26 
    ISSN: 0935-6304
    Keywords: Gas chromatography, glass capillary ; Selective detection ; Nitrated polycyclic aromatic hydrocarbons ; Carbon black ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Glass capillary gas chromatography has been investigated as a method for the analysis of nitrated polycyclic aromatic hydrocarbons (nitro-PAH) using both splitless and on-column injection techniques. The nitro-PAH showed good chromatographic performance and thermal stability under the GC conditions used. Retention times and response factors of several nitro-PAH were compared to those of conventional PAH.Simultaneous flame ionization and thermionic nitrogen selective detection was used to facilitate identification of nitro-PAH in complex samples. The feasibility of the method is demonstrated on two samples of commercial carbon black. Besides 1-nitropyrene several isomeric dinitropyrenes have been identified.
    Additional Material: 7 Ill.
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  • 3
    ISSN: 0935-6304
    Keywords: Thin-layer chromatography, TLC ; Reversed phase TLC ; Chemically bonded stationary phases ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: An overview is given of the literature publisned in the field of thin-layer chromatography on chemically bonded phases. Aspects which merit further attention are: quantitative analysis, organic solvent selection, stationary phase characteristics, surface modification of precoated silica plates, ion-pair chromatography and correlation of thin-layer and column chromatographic data.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0935-6304
    Keywords: Thin-layer chromatography, (HP)TLC ; Pre-chromatographic derivatization ; Quantitation of estriol, cortisol, selenium ; Biological matrix ; Water analysis ; Ready-for-use column extraction ; Fluorescence enhancement ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 33 (1982), S. 647-653 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Corrosion fatigue of plasmanitrided steelThe effect of plasma-nitriding of steel 34 CrAlMo 5 on corrosion fatigue has been investigated in cyclic torsion. The tests were conducted in air, tap water and artifical sea water. Crack initiation and propagation have been studied by means of metallographic and fractographic methods to identify the fatigue mechanisms.Main results may be summarized as follows: The fatigue strength increases by about 40% due to plasma-nitriding over that of nonnitrided steel when tested in air. Even in corrosion environment plasma-nitriding improves remarkably the fatigue strength. The torsional fatigue strength of plasmanitrided specimen is not affected by the presence of tap water. In artifical sea water the distinct fatigue limit disappears. However, the fatigue life of the plasmanitrided specimen increases by factor of 10 compared with that of non-nitrided specimen. The reasons for this improvement were discussed by considering the mechanical and metallurgical aspects of the problems.
    Notes: Das Schwingungsrißkorrosionsverhalten von plasmanitriertem Stahl 34 CrAlMo 5 wurde in Torsionswechselversuchen an Luft, in Leitungswasser und in künstlichem Meerwasser untersucht. Rißbildung und Rißausbreitung wurden mittels metallographischer und fraktographischer Untersuchungsmethoden analysiert. Die Ergebnisse lassen sich folgendermaßen zusammenfassen: Durch das Plasmanitrieren wird an Luft eine Steigerung der Dauerfestigkeit um 40% gegenüber dem unbehandelten Zustand erreicht. Auch bei Einwirkung eines korrosiven Mediums bewirkt die Plasmanitrierschicht eine wesentliche Verbesserung des Dauerschwingverhaltens. Die Torsionswechselfestigkeit des plasmanitrierten Werkstoffes wird von einer Leitungswasserumgebung nicht beeinträchtigt. Im künstlichen Meerwasser existiert sowohl im unbehandelten als auch im plasmanitrierten Werkstoffzustand keine Dauerfestigkeit. Die Lebensdauer des plasmanitrierten Werkstoffes ist jedoch um eine Zehnerpotenz größer als die des unbehandelten Werkstoffes. Für die dargestellten Versuchsergebnisse werden verschiedene Deutungsmöglichkeiten diskutiert.
    Additional Material: 12 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 20 (1982), S. 953-959 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The reorientational relaxation of 9-cyananthracene fluorescent label molecules has been measured in bulk polybutadiene and solutions with cyclohexane by a fluorescent depolarization technique. The procedure adopted consists in the incorporation of an Arrhenius temperature dependence of the orientational relaxation time in the Perrin equation, thus obviating the necessity of an independent determination of the intrinsic polarization ratio P0 and enabling one to obtain the preexponential factors and the activation energies of the reorientational relaxation times. The most noteworthy result in our view is the validity of the Arrhenius equation for the effective microviscosity as opposed to the validity of the Fulcher-Vogel-Tamann equation with a glass point of T0 = 136 K for the shear viscosity of a polymer solution (90%).
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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