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  • Chemistry  (9)
  • Computer Systems
  • SPACE RADIATION
  • 1985-1989  (3)
  • 1980-1984  (6)
  • 1975-1979
  • 1925-1929
  • 1987  (3)
  • 1982  (6)
Collection
Publisher
Years
  • 1985-1989  (3)
  • 1980-1984  (6)
  • 1975-1979
  • 1925-1929
Year
  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 188 (1987), S. 217-226 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A phenomenological model is proposed which considers the polymer as an aggregate of units. The units are composed of two distinct phases  -  amorphous and crystalline. The thermal conductivity of a unit is calculated in terms of those of its constituents. In the undrawn state these units are distributed randomly, and the isotropic thermal conductivity of the bulk results. The development of strong anisotropy in thermal conductivity is explained in terms of the preferred orientation of these units. The structural features of this model are similar to those employed for the interpretation of the mechanical properties. The change in orientation of the units was deduced from the experimental data of birefringence. Finally, the results obtained from the composite model for several semicrystalline polymers are compared with the experimental data and other existing calculations. The model is found to give a fair overall description of the thermal conductivity in the cases of polypropylene, polyoxymethylene, low and high density polyethylene, and polychlorotrifluoroethylene.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 27 (1982), S. 149-159 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Crosslinked polymers based on the condensation of furfural with N-vinylcarbazole and poly(N-vinylcarbazole) were prepared. The effect of variation of furfural concentration on the condensation of furfural with N-vinylcarbazole and its polymer was studied. The polymers were chemically modified into phosphonic acid cation exchange resins. The effects of variation of AlCl3, PCl3, and furfural amounts, reaction time, and rephosphorylation on the synthesis and capacities of cation exchange resins were also studied.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 25 (1987), S. 187-191 
    ISSN: 0887-6258
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 25 (1987), S. 339-352 
    ISSN: 0887-6266
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Poly[(N-benzyldiphenylamino)methane] was synthesized by the condensation polymerization of benzyldiphenylamine and formalin (30% HCOH in water) and examined for electrical and optoelectronic properties. Dark conductivity and photoconductivity of the polymer film were investigated by steady-state measurements. Current-voltage characteristics and intrinsic photoconduction of the polymer in the visible wavelength range were studied. A superlinear current increase is tentatively explained in the light of the Poole-Frenkel effect. Dielectric constant and dielectric loss parameters of the polymer are independent of frequency (50 Hz-10 kHz) and temperature (273-323 K), respectively. The growth and decay rates of the photocurrent depend on the applied voltage, and the photocurrent varies directly with the light intensity. The activation energies for dark conductivity and photoconductivity are 1.16 eV and 1.05 eV, respectively, and the optical energy band gap as evaluated from absorption coefficient spectra is 2.86 eV.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 27 (1982), S. 161-169 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Thermal stabilities of the crosslinked N-vinylcarbazole/poly(N-vinylcarbazole)-furfural polymers and of the phosphonic acid resins prepared thereform were studied by thermogravimetric analysis. The overall thermal stability of the crosslinked polymers is greater than the same for poly(N-vinylcarbazole) and is further improved upon phosphorylation. The resins are stable in 5N acids and water at 100°C. Isothermal oxidative degradation studies of the resins indicate significant increase in the capacities. pH metric titration of the resins shows the presence of mono and dibasic phosphonic acid groups. The resins realize about 90% of their capacities within 2 min of equilibration.
    Additional Material: 6 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 27 (1982), S. 4645-4653 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Crosslinked polystyrene based on condensation of polystyrene and pyromellitic dianhydride has been processed into a sulfonic acid cation exchange resin of improved thermal properties. The resin has been characterized in respect to its structure ion exchange and thermal stability by IR and elemental analysis data, total and salt-splitting capacity measurements, pH-titration characteristics, and TGA and DTA studies.
    Additional Material: 9 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 27 (1982), S. 1823-1825 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 2 Tab.
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 27 (1982), S. 3851-3857 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Polystyrene has been modified by electrophilic substitution reaction with phthalic anhydride and pyromellitic dianhydride. The products have been characterized by physical characteristics, solubility differences, elemental analysis, infrared spectra, ion-exchange capacity, and pH metric titration. The ultimate thermal stabilities of these modified polymers are better than the same for the unmodified polystyrene.
    Additional Material: 3 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 20 (1982), S. 333-339 
    ISSN: 0360-6384
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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