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  • EARTH RESOURCES AND REMOTE SENSING  (148)
  • Analytical Chemistry and Spectroscopy  (98)
  • Chemical Engineering  (59)
  • 1980-1984  (305)
  • 1935-1939
  • 1981  (305)
Collection
Keywords
Publisher
Years
  • 1980-1984  (305)
  • 1935-1939
Year
  • 1
    Electronic Resource
    Electronic Resource
    NQR investigations of 35Cl in crystalline 2,5-dichloro-4-nitroaniline (1981)
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 16 (1981), S. 123-125 
    Details
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Two NQR lines were observed for 35Cl in 2,5-dichloro-4-nitroaniline at room temperature, using a self-quenched super-regenerative spectrometer. Analysis of the Zeeman effect on the two lines using a cylindrical single crystal reveals that the crystal belongs to the monoclinic system. The principal field gradient Z axes enclose an angle of 35° and 28° in the cases of the low and high frequency resonance lines, respectively. The b axis is parallel to 81°, 280°. The unit cell contains either two or a multiple of two molecules. The molecules in the crystal can be arranged into two sets, with the molecular planes in each set being parallel among each other. The angle subtended between the two planes is 159° and each of the planes is inclined to the b axis at an angle of 79.5°. There is an in-plane bending of the two C—Cl bonds by 5.5°. The ionic, single bond and double bond characters of the C—Cl bonds for both chlorines are almost equal, and are in the ratio 24:73:3.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/mrc.1270160212
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    Paper (German National Licenses)
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  • 2
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    Seasat data utilization project (1981)
    In:  CASI
    Details
    Publication Date: 2019-06-28
    Description: During the three months of orbital operations, the satellite returned data from the world's oceans. Dozens of tropical storms, hurricanes and typhoons were observed, and two planned major intensive surface truth experiments were conducted. The utility of the Seasat-A microwave sensors as oceanographic tools was determined. Sensor and geophysical evaluations are discussed, including surface observations, and evaluation summaries of an altimeter, a scatterometer, a scanning multichannel microwave radiometer, a synthetic aperture radar, and a visible and infrared radiometer.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
    Type: NASA-CR-168557 , REPT-622-233
    Format: application/pdf
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    NASA TECHNICAL REPORTS
  • 3
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    Studies of high latitude current systems using MAGSAT vector data (1981)
    In:  CASI
    Details
    Publication Date: 2019-07-13
    Description: The magnetic disturbance fields caused by global external current systems are considered with particular emphasis on improving the understanding of the physical processes which control high latitude current systems. Following processing the MAGSAT data were routinely plotted in the Universal Time (UT) format as well as in a polar plot format. The H'D'U' coordinate system, was adopted as the standard for representing the MAGSAT residual magnetic field vectors. A data file was generated and the TPOLAR computer code was developed to determine from the orbital elements, the time, latitude, and MLT of the extremum latitude of each transpolar segment of orbit. The precision of the vector data set from MAGSAT prompted an extended exploratory phase for data analysis procedures, modeling techniques and phenomenology.
    Keywords: EARTH RESOURCES AND REMOTE SENSING
    Type: E82-10188 , NASA-CR-168616 , NAS 1.26:168616 , PR-3
    Format: application/pdf
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    NASA TECHNICAL REPORTS
  • 4
    Electronic Resource
    Electronic Resource
    Fused silica capillary column GC/MS for the analysis of priority pollutants (1981)
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 366-384 
    Details
    ISSN: 0935-6304
    Keywords: GC/MS ; Capillary columns, fused silica ; Priority pollutants ; Quantitation ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Operational characteristics have been determined for fused silica capillary column (FSCC) GC/MS as applied to “extractable” priority polutants. Chromatographic data show excellent relative retention time (RRT) intralaboratory precision and interlaboratory accuracy when multiple internal standards are empolyed. Potential chromatographic problems, such as column overload and “double peaking”, are addressed. Response factor relative standard deviations (RSD) at 50 ng for most of the extractable priority pollutants over the long term indicated precise determination (i.e. RSD generally ≤ 10%). Linearity was demonstrated over two orders of magnitude for FSCC GC/MS analysis of compounds with relatively low and high RF (response factor) values. Potential quantitative problems, such as saturation, are discussed. For certain aromatic priority pollutants interlaboratory RF agreement was observed. This was noted as perhaps the most important property of FSCC GC/MS analysis when the multiple internal standard approach is utilized. Determinations of extractable priority pollutants are directly compared for paced column GC/MS and FSCC GC/MS analysis of separate and composited extracts. For six extracts analyzed in triplicate, the latter configuration was shown to produce more consistent results. In view of the superior analysis logistics of composite extract FSCC GC/MS analysis, this approach was established as the preferred method for the analysis of priority pollutants classified as extractable.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jhrc.1240040803
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  • 5
    Electronic Resource
    Electronic Resource
    Obtaining quantitative data for PNAs with capillary column gas chromatography using split and splitless injectionWork supported by the U. S. Department of Energy Under Contract DE-AC06-76RLO 1830. (1981)
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 638-641 
    Details
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Capillary, fused silica ; Split injection ; Splitless injection ; Polynuclear aromatic hydrocarbons, quantitation ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jhrc.1240041206
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  • 6
    Electronic Resource
    Electronic Resource
    Vapor liquid equilibria up to 100 MPa: A new apparatus (1981)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 27 (1981), S. 203-207 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new static cell for vapor-liquid equilibria up to 100 MPa between 233 and 433 K is presented. A detachable sampling microcell and a special chromatographic injector are used in a new sampling system suitable for gas chromatographic analysis of mixtures with high boiling components. The test system is N2 - n-Heptane at 305.45 K.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690270205
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  • 7
    Electronic Resource
    Electronic Resource
    Reaction regimes in coal oxidation (1981)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 27 (1981), S. 920-927 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A series of seven coals were oxidized in a fixed bed reactor to determine the controlling reaction regimes during mild coal oxidation. The effects of coal porosity and particle size, reactor temperature, and oxygen partial pressure were evaluated. The results show that coal-oxygen reactions are controlled by the rate of internal gaseous diffusion for most coals, and by the rate of chemical reaction for the most porous coal of the set tested. Particle size effects also suggest internal diffusional control. Determinations of cumulative oxygen deposition indicate that surface areas several orders of magnitude greater than the superficial surface can participate in oxidation reactions, putting in doubt the applicability of the model previously derived by Kam et al. (1976a) for external mass transfer control.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690270607
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  • 8
    Electronic Resource
    Electronic Resource
    Effect of chemical modifiers on borax crystal growth, nucleation and habit (1981)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 27 (1981), S. 92-99 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effects on the fine-crystal CSD of various surface active and ionic additives were studied for the sodium tetraborate decahydrate (borax) system. The organic modifiers used were effective at the ppm level. Surface active agents inhibited nucleation rate, while ionic additives increased nucleation. A simultaneous reduction in both the linear-crystal growth rate and the degree of polycrystalline growth was observed in both cases. These effects correlated with modifier concentration in the liquor, but not with modifier/solids ratio. Borax exhibits classical magma and RPM-dependent secondary nucleation and the results were well-correlated with a conventional power-law kinetic model.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690270114
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  • 9
    Electronic Resource
    Electronic Resource
    An explicit equation for particle settling velocities in solid-liquid systems (1981)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 27 (1981), S. 1043-1044 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690270629
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  • 10
    Electronic Resource
    Electronic Resource
    A random pore model for fluid-solid reactions: II. Diffusion and transport effectsPart I of this paper appeared in AIChE J., 26, 379 (1980) (1981)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 27 (1981), S. 247-254 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The prior random pore model for kinetically controlled fluid-solid reaction (Bhatia and Perlmutter, 1980) is generalized to include transport effects arising from boundary layer, intraparticle, and product layer diffusion. Numerical solutions are presented for a variety of conditions. The results show that the rate and surface area maxima predicted in the kinetic regime are shifted to lower conversions as intraparticle or product layer diffusional resistances increase. In addition, with increasing temperature a decrease in the overall reaction surface is predicted, in agreement with experimental findings (Kawahata and Walker, 1962).For reactions accompanied by an increase in the volume of the solid phase, it is shown that incomplete conversion may be expected, the ultimate conversion decreasing with an increase in the intrapellet diffusional resistance. Optimal temperatures for such reactions are also identified.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690270211
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