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  • Analytical Chemistry and Spectroscopy  (1)
  • 2000-2004
  • 1980-1984  (1)
  • 1981  (1)
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  • 2000-2004
  • 1980-1984  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    13C NMR and ESR spectroscopic investigations on tert-butyl-substituted cyclopentadienones (1981)
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 17 (1981), S. 6-9 
    Details
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 13C NMR spectra of 11 di-, tri- and tetra-tert-butyl-substituted cyclopentadienones are discussed with respect to charge distribution and substituent effects. The chemical shifts of the unsubstituted cyclopentadienone, calculated from substituent increments, are in good agreement with published CNDO calculations and can be rationalized by the inductive effect of the carbonyl group. In addition, the ESR signals shown by some of the cyclopentadienones are described, and possible reasons for their appearance are discussed.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/mrc.1270170103
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