ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The unimolecular and collision induced fragmentation reactions of 19 polycyclic aromatic hydrocarbons have been investigated, using B/E linked scans, accelerating voltage scans, and measurements of appearance energies. From the point of view of simple analytical fingerprinting within isomeric series, B/E linked scans without collision gas offered the best compromise. Attempts to correlate trends observed in fragmentation intensities with various molecular parameters were generally unsuccessful, although some tentative conclusions have been drawn. The evidence concerning fragmentation mechanisms and ion structures is also discussed.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210150904
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