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  • Wiley-Blackwell  (7)
  • 1995-1999
  • 1980-1984  (7)
  • 1980  (7)
  • 1
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 15 (1980), S. 63-85 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: An analysis of axisymmetric free jet impingement on to finite disks was performed using the finite element method. The method employed the velocity potential as the dependent variable and six-node triangle elements to represent the region of flow. The analysis was divided into three parts corresponding to three distinct regions of the flow: (1) In the disk region, the free jet impinged on to a finite disk which was oriented normal to the flow. The jet was subjected to zero or normal gravity and to surface tension effects of varying degrees. (2) Upon leaving the disk region, the jet entered the plume region where it was acted upon internally by surface tension and externally by zero or normal gravity. (3) In the collision region, the flow from the plume region collided symmetrically at some downstream area about the axis of symmetry. The major result achieved from this investigation was the development of techniques to locate the free surface in all three regions for a range of conditions. The velocity profiles along selected lines of constant values of the potential were determined, and a successful comparison was made between the numerical results and existing experimental data.
    Additional Material: 20 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 31 (1980), S. 21-27 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Corrosion by acids formed by oxidation of bitumineous roof coveringsIn recent years there has been an increased number of case histories involving metallic roof draining systems in connection with bitumineous materials. An evaluation of 64 histories has shown that 60% of the cases could be attributed to unprotected bitumineous coatings, mastix and undefined special paint coats, 24% to weld-seems without slate covering and about 16% to inadequately sanded roof areas. No damages were counted in the case of roofs with adequate gravel or slate covering. Short-time weathering in the laboratory has confirmed these findings. It could be shown that bitumineous materials are oxidized during weathering and formed carbonic acid. It has further been shown that reaction products of chemicals used for blowing or improving bitumineous materials are not the cause of such damages. The oxidation and thus the formations of acids can be used by adequate sanding of the bitumineous materials so that the damage to roof draining systems can be excluded.
    Notes: In den letzten Jahren kam es vermehrt zu Schäden an Dachentwässerungssystemen aus metallischen Werkstoffen in Verbindung mit bituminösen Baustoffen.Eine Untersuchung von 64 Schadensfällen ergab, daß 60% der Schäden auf ungeschützte bituminöse Anstriche, Spachtelmassen und nicht definierte Spezialanstriche, 24% auf ungeschützte, d. h. nicht beschieferte Schweißbahnen und etwa 16% auf Dachflächen mit lückenhafter Bestreuung entfallen. Dagegen traten bei ordungsgemäß bekiesten oder beschieferten Dachflächen keine Schäden auf. Im Labor durchgeführte Kurzzeitbewitterungsprüfungen bestätigten diese Untersuchung. Es zeigte sich, daß Bitumen unter Einwirkung von Witterungseinflüssen oxidiert und dabei Carbonsäuren entstehen. Es konnte weiterhin geklärt werden, daß Reaktionsprodukte von Chemikalien, die beim Blasen oder zur Vergütung von Bitumen eingesetzt werden, als Verursacher ausscheiden.Nur eine ordungsgemäße Bestreuung schwächt die Oxidation und damit die Säurebildung, so daß eine Gefährdung metallischer Dachentwässerungssysteme ausgeschlossen werden kann.
    Additional Material: 1 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 113 (1980), S. 2221-2226 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Metabolites of Microorganisms, 195. The Structure of Ophiocordin, an Antibiotic with Antifungal ActivityThe structure of the antibiotic Ophiocordin (9), which exhibits antifungal activity, was elucidated by chemical degradation, mass spectrometry, and NMR. Ophiocordin contains a novel 3-amino-hexahydro-4-hydroxyazepin system (5), which is esterified with 4-hydroxybenzoic acid and connected to 3,3′,5′-trihydroxy-2,4′-carbonylbis[benzoic acid] (7) via an amide bond between the 1-carboxy group and the amino group of the azepin system.
    Notes: Die Konstitution des antifungisch wirksamen Antibiotikums Ophiocordin (9) konnte durch chemischen Abbau, Massenspektrometrie und Kernresonanz aufgeklärt werden. Ophiocordin enthält ein neuartiges 3-Aminohexahydro-4-hydroxyazepin-System (5), an das 4-Hydroxybenzoesäure esterartig und 3,3′,5′-Trihydroxy-2,4′-carbonylbis[benzoesäure] (7) über die Carboxylgruppe in 1-Stellung säureamidartig gebunden ist.
    Additional Material: 2 Ill.
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  • 4
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
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  • 5
    ISSN: 0570-0833
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 18 (1980), S. 1383-1391 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A novel planar ↔ nonplanar visual thermochromic conformational transition of polydiacetylene molecules in poor solvents is reported. The conformational transition is associated with both a color change (blue or red ↔ yellow) and a change in the state; the yellow solution (liquid) transforms to a blue or red gel (solid). The color transition occurs within a narrow range of temperature and has a large associated hysteresis. The enthalpy of the conformational transition is 29 kJ/mole of repeat unit. Fourier-transform infrared studies show that molecules acquire a planar conformation in red or blue gels by formation of intramolecular H bonds between the adjacent substituent groups. Virtually all H bonds break (a nonplanar conformation) when the gels turn into yellow solutions.
    Additional Material: 6 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 9 (1980), S. 230-238 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The IR spectra (1400 cm-1 to 160 cm-1) of the gases at ambient temperature and the Raman spectra (below 1400 cm-1) of the liquids near -196°C are reported for CF3OF and CF3OCl. All fundamentals are assigned under Cs symmetry and the results of a normal coordinate analysis are presented. The assignments of Smardzewski and Fox are adopted with one exception for both CF3OF and CF3OCl: the CF3 rock of A″ symmetry is assigned near 430 cm-1 and the two bands between 200 cm-1 and 300 cm-1 are assigned to an A′ fundamental, involving CF3 rocking and COX bending and a Δν=2 transition in the CF3 torsion. An extra band at 548 cm-1 in the Raman spectrum of liquid CF3 COl near -196°C is assigned to a CF3OCl⃛Cl2 complex. The values of the force constants d(OX) for CF3OX molecules are suggested to be near those for X2O molecules. More than half the normal modes of A′ symmetry show extensive mixing of symmetry coordinates. In some of these cases the symmetry coordinate for which the normal mode is named is the largest but not the dominant contributor to the potential energy distribution, while in others this symmetry coordinate is not even the largest contributor to the potential energy distribution. No normal modes of A′ symmetry are present in which ν(CO), δs(CF3), δ(COX), or δ(CF3) symmetry coordinates are dominant, and the mode conventionally labeled as v(CO) should be labeled as νs(CF3). For the remaining A′ normal modes and all the A″ normal modes, the symmetry coordinate for which the normal mode is named is dominant in the potential energy distribution.
    Additional Material: 3 Ill.
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