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  • Polymer and Materials Science  (214)
  • Chemical Engineering  (60)
  • 1975-1979  (274)
  • 1970-1974
  • 1950-1954
  • 1979  (274)
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Publisher
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  • 1975-1979  (274)
  • 1970-1974
  • 1950-1954
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  • 1
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A study has been made of the structure and properties of alternating equimolar and random copolymers of vinylcyclohexanne and α-methylvinylcyclohexane with acrylonitrile using infrared and 1H-NMR spectroscopy methods, as well as x-ray diffraction and differential thermal analyses. The spectral methods allowed an estimation of the composition and distribution of comonomer units in the copolymer macrochains. The thermal stability of alternating copolymers was found to be higher than that of polyacrylonitrile. Alternating and random copolymers are amorphous products with various dimensions of crystallites. Information on the molecular motion intensity and temperatures of structural transitions in copolymer macrochains was obtained by the spin-probe technique.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Transport properties were determined for various Loeb-type membranes which exhibit strong structure differences from one to another. Using linear relations of thermodynamics of irreversible processes for the homogeneous ones, correlations were found between the specific transport coefficients and the states of water in the membrane medium. In the case of heterogeneous membranes a schematic multilayer model, using in an appropriate way Darcy's law, was worked out in accordance with electron micrographs of membrane cross sections. It enables us to correlate the membrane hydraulic permeability with the relative extent of four typical structures A, B, C, and D. In addition, this model provides both the hydraulic specific permeabilities of these types of structure and their hydration characteristics.
    Additional Material: 8 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 23 (1979), S. 777-789 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Ultrahigh molecular weight polyethylene is now extensively used in total joint replacements, and there is ample clinical evidence that this material wears at a significant rate in such applications. Six commercially available total hip replacements were subjected to an accurate simulation of clinical mechanical and chemical conditions, and the wear behavior of the polyethylene components was analyzed by friction coefficient measurements and scanning electron micrography of the wear surfaces. The results indicate that all of the proposed wear mechanisms excepting adhesive and abrasive wear may be eliminated. It is highly likely that abrasion fatigue and related phenomena are central to the wear process in many prostheses, but the wear process may be ultimately determined in many cases by the type of defects present in the manufactured material.
    Additional Material: 9 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 19 (1979), S. 162-165 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The thermal and mechanical degradation of glassy polystyrene has been studied by Fourier Transform Infrared, FT-IR, spectroscopy. Using difference spectroscopy we have found that the products formed from these two modes of degradation were significantly different. This result is in contrast with other workers who found similar products for the thermal and mechanical degradation of polystyrene by mass spectroscopy. Our result suggests a reassessment of the thermal activation mechanism for mechanically-induced bond scission. We have also found that the distribution of oxidation products appears to depend upon the environment in which the polymer is mechanically degraded. Finally, we have demonstrated the utility of FT-IR spectroscopy for studying the mechanical degradation of polymers.
    Additional Material: 5 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 19 (1979), S. 1046-1053 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The hot drawing of extruded composite sheets can be used to control the orientation of both matrix and reinforcing fibers. A study was made of the effect of draw ratio on the properties of an extruded polystyrene sheet containing 0 to 1 percent of short glass fibers. An increase in draw ratio resulted in an increase in fiber orientation. A model of a rigid fiber rotating in an elongational flow field was used to describe the effect of draw ratio on the final orientation distribution. An increase in draw ratio also caused an increase in the amount of fiber breakage. A shear-lag analysis was used to estimate the extent of damage as a function of draw ratio. It was also found that the mechanical properties were dependent upon both the draw ratio and fiber concentration.
    Additional Material: 14 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 25 (1979), S. 759-762 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Calculation of the phase diagram for saturated aqueous multi-ion solutions of strong electrolytes, based upon use of the thermodynamic solubility products, is illustrated for the four-ion system: Na+, K+, Mg++, SO4=. Solid phases are identified along with the ion concentrations of the associated saturated solutions.
    Additional Material: 1 Ill.
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  • 7
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Internal reflectance Fourier transform infrared (FT-IR) spectra of tetraglycidyl diaminodiphenylmethane (TGDDM) cured with diaminodiphenyl sulfone (DDS) obtained before and after exposure to the combined effect of stress, elevated temperature, and moisture (STM), elevated temperature and moisture (TM), or stress and elevated temperature (ST) environments were used to search for evidence of irreversible chemical changes in epoxy resins. These changes were compared with the infrared changes observed during the late stages of curing. The infrared intensities of the bands attributed to the sulfone group are sensitive to chemical changes and moisture content, which suggests their potential use as molecular monitors within the epoxy network. The results of eight experimental series provide spectroscopic evidence indicating that exposure of epoxy specimens to STM and TM environments that greatly exceed anticipated service conditions results in detectable rupture of chemical bonds in the polymer network. The extent of bond rupture is independent of the applied stress in the 0-90 kg/cm2 range. Internal swelling stresses are therefore believed responsible for the observed bond cleavages. Spectral evidence indicates that postcure reactions are the most prominent chemical changes induced by exposure of epoxy specimens to the ST, SM, M, and T environments.
    Additional Material: 13 Ill.
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  • 8
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Glucose oxidase, catalase, and bovine serum albumin were co-immobilized with glutaraldehyde around a platinum screen or around a single platinum - iridium wire. The potential difference between this dual enzyme electrode and a Ag/AgCl reference electrode was proportional to the logarithm of the glucose concentration over the range from 10 to about 150 mg glucose per 100 ml in buffered solution at pH 7.4 and 37°C. The enzyme electrode responded in serum only if coated with a semipermeable film, such as cellulose acetate, to exclude serum macromolecules. The potentiometric results were similar to those obtained with the two enzymes co-immobilized in polyacrylamide gel around a platinum screen or with only one of the enzymes, glucose oxidase, covalently coupled to a platinum screen. The results so far suggest that these potentiometric enzyme electrodes may have sufficient specificity for glucose for development of a continuous in vivo glucose sensor.
    Additional Material: 2 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 13 (1979), S. 251-263 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: The fatigue behavior of alumina and bioglass-coated alumina was determined in air and biological test environments by the dynamic fatigue test technique in which strength is measured as a function of stressing rate. The good correlation found between the test data and fracture mechanics theory indicates that fatigue failure is controlled by the slow crack growth of preexisting flaws and that fracture mechanics theory can be used in making failure predictions for alumina and bioglass-coated alumina in biological environments. Thus, it is believed that lifetime predictions can be made for ceramic implants on the basis of short-term test data utilizing fracture mechanics principles.
    Additional Material: 6 Ill.
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  • 10
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Measurements of translational diffusion coefficients by quasielastic laser light scattering, sedimentation coefficients, and intrinsic viscosities at zero shear of proteoglycan subunit fraction A1-D1-D1 isolated from bovine nasal septa are reported. Molecular weights and hydrodynamic dimensions are compared with those expected on the basis of structural models previously proposed. Comparison of the concentration dependence of the diffusion coefficient in the presence of NaCl and GdnHCl leads to the conclusion that significant self-association behaviour of subunit occurs in the absence of GdnHCl. In the absence of added salt, anomalous nonlinear concentration dependence of Dt estimated from wide-angle light-scattering experiments is observed. In addition, Dt apparently becomes angle dependent. These results are interpreted in terms of the perturbation of normal translational diffusion of the monomer by strong repulsive intermolecular interactions due to the combined effects of long-range electrostatic forces and macromolecular congestion at higher concentrations. By carrying out experiments at small scattering angles, it is possible to determine Dt0 for proteoglycan subunit in the absence of supporting electrolyte. Titration of a dilute solution of subunit with hyaluronic acid results in a sigmoidal behaviour of the Stokes radius, indicating the formation of complexes of higher molecular weight results from the noncovalent association of proteoglycan subunits with hyaluronate. Observation of Dt appears to provide a useful method for studying the proteoglycan subunit-hyaluronate interactions.
    Additional Material: 14 Ill.
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