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  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 19 (1979), S. 1098-1103 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Neck-in and maximum stress were studied in a tape-drawing experiment using a 3.5 MI low density polyethylene at 300°C. The conditions of the experiment were designed to reproduce closely those found in extrusion coating lines. The maximum stress was found to increase roughly with the 1.6 power of the drawdown ratio and the 1.0 power of the extrusion speed over a stress range of 4 × 103 to 5 × 105 Pa produced by drawdown ratios ranging from 2 to 22 and extrusion speeds of 2.3 to 6.1 cm s-1. The neck-in decreased weakly with drawdown ratio at low extrusion speed and with extrusion speed at constant drawdown ratio. After carefully characterizing the test resin in shear and extension, the similarities between predicted pure-shear (planar extension) transients and the tape experiments were studied. It was found that the trends, but not the magnitude of the experimental maximum stress were quite similar to the calculated longitudinal stress in pure shear. The behavior of the transverse to longitudinal stress ratio in pure shear was similar in behavior to the neck-in results, but considerable improvement was achieved by adding in a decayed stress from a simple-shear transient to simulate the conditions produced by the extrusion die. The philosophy of purposefully studying similarities between transient, pure or simple deformations and steady, complex processes is discussed.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    X-Ray Spectrometry 8 (1979), S. 196-198 
    ISSN: 0049-8246
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: An outline for a simple pulse spectroscope which attaches to a standard laboratory CRO is presented. The peak amplitude (voltage) of each pulse from the linear amplifier of a single channel X-ray analyser is stored for the duration of one oscilloscope trace. For each amplifier pulse, input from the discriminator is tested and if there is coincidence of pulses the oscilloscope beam is blanked for approximately the first 2 cm of its traverse across the screen. Repetition of pulses forms a pulse height distribution with a rectangular dark area marking the position of the discriminator window.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 17 (1979), S. 3315-3328 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polymeric methacrylates functionalized with free methacryloyl groups are efficiently crosslinked in the presence of transition-metal carbonyls on UV irradiation of the polymeric solid. The reaction proceeds by a radical chain mechanism with a kinetic chain length of about 10 in a solvent-free polymer containing 10-3 mole of methacryloyl groups per cm3. The chain length increases steeply when the glass transition of the polymer is reached, either by plastification or by an increase in temperature. The temperature dependence of the crosslinking yield below the glass transition is consistent with an activation energy of about 9 kcal mole-1. The addition of acrylic monomers enhances chain propagation by up to an order of magnitude. Postirradiative crosslinking in the matrix comes to a standstill well before all acrylic groups or radicals have been exhausted: if, after cessation of the primary reaction, the matrix is briefly heated, a second crop of crosslinks is obtained without further exposure. The system behaves thus as if the radicals had been removed into traps from which they can be set free by thermal activation. From an analysis of the reaction kinetics it appears that in the glassy polymer 90% of the radicals are inactivated in this way. Radical recombination, however, is the principal mechanism of chain termination above the glass transition. From the kinetic data, diffusion coefficients for polymer-bound groups are found to be in the range of 10-17-10-16 cm2 sec-1 in the glassy polymer at room temperature. They are of the order of 10-14 cm2 sec-1 in plasticized films above the glass transition.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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